首页|基于一锅法制备的Ag/AgCl/CeO2复合纳米材料及其光催化有机物降解性能

基于一锅法制备的Ag/AgCl/CeO2复合纳米材料及其光催化有机物降解性能

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采用一锅法制备Ag/CeO2光催化剂,并通过原位氧化法进一步制备Ag/AgCl/CeO2复合材料,使用XRD、SEM对Ag/AgCl/CeO2复合纳米材料的结构、形貌进行表征,采用橙黄Ⅱ、罗丹明6G、诱惑红等有机染料测试复合材料的光催化性能。结果表明:AgCl在Ag/AgCl中占比80%时,Ag/AgCl/CeO2复合材料的光催化性能最佳,在模拟太阳光辐照6 min后能降解93% 的橙黄Ⅱ,且在4次循环8 min内能降解90% 以上的橙黄Ⅱ,在紫外-可见混合光照60 min后,能降解约90% 的罗丹明6G和诱惑红。Ag/AgCl/CeO2复合材料具有优异的光催化活性的主要原因是贵金属Ag的局域表面等离子共振效应以及金属/半导体异质结结构。
Preparation of Ag/AgCl/CeO2 Composite Nanomaterials and Photocatalytic Degradation of Their Organic Compounds Application Based on One-Pot Method
The Ag/CeO2 photocatalyst was prepared by one-pot method,and the Ag/AgCl/CeO2 composite was further prepared by in-situ oxidation method.The structure and morphology of the Ag/AgCl/CeO2 composite nanomaterials were characterized by XRD and SEM.The photocatalytic properties of the composites were tested with organic dyes such as Orange Ⅱ,Rhodamine 6G and temptation Red.The results showed that Ag/AgCl/CeO2 composite had the best photocatalytic performance when AgCl accounted for 80% of Ag/AgCl.After 6 min of simulated sunlight irradiation by xenon lamp,93% of orange Ⅱ could be degraded,and the degradation rate of Orange Ⅱ could reach more than 90% within 8 min of 4 cycles.About 90% Rhodamine 6G and temptation Red can be degraded after 60 min of UV-VIS mixed light.The excellent photocatalytic activity of Ag/AgCl/CeO2 composites is mainly due to the localized surface plasmon resonance (SPR) of the precious metal Ag effects and metal/semiconductor heterostructure.

one-pot methodAg/CeO2precious metal photocatalystAg/AgCl

陈垚、王瑾萱、方嫣然、肖乐欣、杨纯、刘军

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湖南工业大学生命科学与化学学院 湖南 株洲 412007

一锅法 Ag/CeO2 贵金属光催化剂 Ag/AgCl

湖南省自然科学基金资助面上项目湖南省自然科学基金资助面上项目湖南省教育厅科学研究基金资助优秀青年项目

2024JJ51242024JJ512623B0564

2024

包装学报
湖南工业大学

包装学报

影响因子:0.509
ISSN:1674-7100
年,卷(期):2024.16(4)