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醋酸纤维衍生的石墨碳作为锂离子电池的负极材料

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随着人们对环境安全认知的不断进步,如何将废弃的卷烟滤棒转化为高价值产品已成为人们关注的焦点.基于此,根据废弃卷烟滤棒(discarded cigarette filters记作DCFs)中醋酸纤维结构和形貌具有一致性的特点,在高压下对DCFs进行了热解研究.其中,50 MPa和 1 000 oC下仅需要 15 min即可制备出一种网状结构的石墨碳材料(记作HP-1000),其收益率高达41.5%.作为锂离子电池的负极材料,HP-1000展现出良好的比容量和倍率性能,特别是在5C下循环获得了105 mAh g-l的比容量.因此,这项工作不仅解决了多年来棘手的卷烟滤棒废弃物对环境影响问题,同时也为储能领域提供了高性能和廉价的石墨碳负极材料.
Graphite Carbon Derived from Acetate Fiber as a Negative Electrode Material for Lithium-ion Batteries
As awareness of environmental safety continues to advance,the transformation of discarded cigarette filter(DCFs)into high-value products has emerged as a focal point of interest.Leveraging the consistent structure and mor-phology of acetate fibers within DCFs,pyrolysis studies were conducted on WCFs under high pressure.Specifically,a network-structured graphite carbon material(designated as HP-1000)was successfully synthesized within 15 minutes at 50 MPa and 1 000 ℃,yielding a remarkable 41.5%of the initial mass.When employed as a negative electrode material in lithium-ion batteries,HP-1000 demonstrated impressive specific capacity and rate performance,achieving a specific capacity of 105 mAh g-1 after cycling at a high rate of 5 C.Consequently,this research not only addresses the persistent environ-mental challenge posed by DCF waste but also contributes to the energy storage field by offering a high-performance and cost-effective graphite carbon negative electrode material.

acetate fiberwaste materialslithium ion batterygraphite carbonpressure pyrolysis

胡宁、朱良华、王超、李娜、秦杰明

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长春理工大学 材料科学与工程学院,长春 130022

吉林烟草工业有限责任公司,长春 130031

醋酸纤维 废弃物 锂离子电池 石墨碳 压力热解

吉林烟草工业有限责任公司科技项目吉林省发改委创新能力建设项目

KJXM-2022-072024C018-1

2024

长春理工大学学报(自然科学版)
长春理工大学

长春理工大学学报(自然科学版)

CSTPCD
影响因子:0.432
ISSN:1672-9870
年,卷(期):2024.47(5)