长春理工大学学报(自然科学版)2024,Vol.47Issue(5) :57-64.

醋酸纤维衍生的石墨碳作为锂离子电池的负极材料

Graphite Carbon Derived from Acetate Fiber as a Negative Electrode Material for Lithium-ion Batteries

胡宁 朱良华 王超 李娜 秦杰明
长春理工大学学报(自然科学版)2024,Vol.47Issue(5) :57-64.

醋酸纤维衍生的石墨碳作为锂离子电池的负极材料

Graphite Carbon Derived from Acetate Fiber as a Negative Electrode Material for Lithium-ion Batteries

胡宁 1朱良华 2王超 2李娜 2秦杰明1
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作者信息

  • 1. 长春理工大学 材料科学与工程学院,长春 130022
  • 2. 吉林烟草工业有限责任公司,长春 130031
  • 折叠

摘要

随着人们对环境安全认知的不断进步,如何将废弃的卷烟滤棒转化为高价值产品已成为人们关注的焦点.基于此,根据废弃卷烟滤棒(discarded cigarette filters记作DCFs)中醋酸纤维结构和形貌具有一致性的特点,在高压下对DCFs进行了热解研究.其中,50 MPa和 1 000 oC下仅需要 15 min即可制备出一种网状结构的石墨碳材料(记作HP-1000),其收益率高达41.5%.作为锂离子电池的负极材料,HP-1000展现出良好的比容量和倍率性能,特别是在5C下循环获得了105 mAh g-l的比容量.因此,这项工作不仅解决了多年来棘手的卷烟滤棒废弃物对环境影响问题,同时也为储能领域提供了高性能和廉价的石墨碳负极材料.

Abstract

As awareness of environmental safety continues to advance,the transformation of discarded cigarette filter(DCFs)into high-value products has emerged as a focal point of interest.Leveraging the consistent structure and mor-phology of acetate fibers within DCFs,pyrolysis studies were conducted on WCFs under high pressure.Specifically,a network-structured graphite carbon material(designated as HP-1000)was successfully synthesized within 15 minutes at 50 MPa and 1 000 ℃,yielding a remarkable 41.5%of the initial mass.When employed as a negative electrode material in lithium-ion batteries,HP-1000 demonstrated impressive specific capacity and rate performance,achieving a specific capacity of 105 mAh g-1 after cycling at a high rate of 5 C.Consequently,this research not only addresses the persistent environ-mental challenge posed by DCF waste but also contributes to the energy storage field by offering a high-performance and cost-effective graphite carbon negative electrode material.

关键词

醋酸纤维/废弃物/锂离子电池/石墨碳/压力热解

Key words

acetate fiber/waste materials/lithium ion battery/graphite carbon/pressure pyrolysis

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基金项目

吉林烟草工业有限责任公司科技项目(KJXM-2022-07)

吉林省发改委创新能力建设项目(2024C018-1)

出版年

2024
长春理工大学学报(自然科学版)
长春理工大学

长春理工大学学报(自然科学版)

CSTPCD
影响因子:0.432
ISSN:1672-9870
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