首页|Particle agglomeration and inhibition method in the fluidized pyrolysis reaction of waste resin

Particle agglomeration and inhibition method in the fluidized pyrolysis reaction of waste resin

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This work investigated the pyrolysis reaction of waste resin in a fluidized bed reactor.It was found that the pyrolysis-generated ash would adhere to the surface of ceramic particles,causing particle agglom-eration and defluidization.Adding kaolin could effectively inhibit the particle agglomeration during the fluidized pyrolysis reaction through physical isolation and chemical reaction.On the one hand,kaolin could form a coating layer on the surface of ceramic particles to prevent the adhesion of organic ash generated by the pyrolysis of resin.On the other hand,when a sufficient amount of kaolin(>0.2%(mass))was added,the activated kaolin could fully contact with the Na+ions generated by the pyrolysis of resin and react to form a high-melting aluminosilicate mineral(nepheline),which could reduce the formation of low-melting-point sodium sulfate and thereby avoid the agglomeration of ceramic particles.

Pyrolysis reaction of waste resinFluidizationParticle agglomerationKaolin

Congjing Ren、Peng Zhang、Qi Song、Zhengliang Huang、Yao Yang、Yongrong Yang

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Ningbo Innovation Center,Zhejiang University,Ningbo 315100,China

College of Chemical and Biological Engineering,Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology,Zhejiang University,Hangzhou 310027,China

support and encouragement of the Joint Funds of the National Natural Science Foundation of ChinaMajor Research Project of National Natural Science Foundation of China

U21B209591834303

2024

中国化学工程学报(英文版)
中国化工学会

中国化学工程学报(英文版)

CSTPCDEI
影响因子:0.818
ISSN:1004-9541
年,卷(期):2024.67(3)
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