中国化学工程学报(英文版)2024,Vol.71Issue(7) :148-160.DOI:10.1016/j.cjche.2024.04.014

Multiple factors influencing high-purity indium electrolytic refining

Hong-Qiang Fan Fei Li Hong-Xing Zheng Wu-ji Pan Mei-Zhen Wu Yashar Behnamian Ju-Bo Peng Dong-Hai Lin
中国化学工程学报(英文版)2024,Vol.71Issue(7) :148-160.DOI:10.1016/j.cjche.2024.04.014

Multiple factors influencing high-purity indium electrolytic refining

Hong-Qiang Fan 1Fei Li 1Hong-Xing Zheng 1Wu-ji Pan 1Mei-Zhen Wu 2Yashar Behnamian 3Ju-Bo Peng 2Dong-Hai Lin4
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作者信息

  • 1. State Key Laboratory of Advanced Special Steel&School of Materials Science and Engineering,Shanghai University,Shanghai 200444,China;Shanghai Engineering Research Center for Integrated Circuits and Advanced Display Materials,Shanghai University,Shanghai 200444,China
  • 2. Research&Development Center,Yunnan Tin Group (Holding) Limited Company,Kunming 650032,China
  • 3. Department of Chemical and Materials Engineering,University of Alberta,Edmonton T6G 2V4,Alberta,Canada
  • 4. School of Energy and Materials,Shanghai Key Laboratory of Engineering Materials Application and Evaluation,Shanghai Polytechnic University,Shanghai 201209,China
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Abstract

The effects of various contaminants in the electrolytic refinement of indium were investigated using a glow discharge mass spectrometer (GDMS). The effects of several factors such as the indium ion (In3+) concentration,the sodium chloride (NaCl) concentration,the current density,the gelatin concentration,the pH,and the electrode distance,were examined. Significant variations in impurity levels concerning gelatin concentration were observed. Both the gelatin and In3+concentration were moderately positively correlated with the Pb content. The Sb concentration was associated positively with the NaCl concen-tration,while the Ti concentration had an adverse correlation with the NaCl concentration. The Bi element content was positively linked to the electrode distance. As the current density increased,Cu,Pb,and Bi impurities initially rose and then eventually declined. Notably,a critical current density of 45 A·m-2 was identified in this behavior.

Key words

High-purity indium/Electrolysis/Multiple factors/Electrochemistry/Purification

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基金项目

National Natural Science Foundation of China(52074180)

Science and Technology Major Project of Yunnan Province(202302AB080020)

Independent Research Project of State Key Laboratory of Advanced Special Steel,Shanghai Key Laboratory of Advanced Ferrometa(SKLASS 2023-Z07)

Science and Technology Commission of Shanghai Municipality(19DZ2270200)

Program for Professor of Special Appointment(Eastern Scholar)at SIHL,Shanghai Sailing Program(19YF1416500)

出版年

2024
中国化学工程学报(英文版)
中国化工学会

中国化学工程学报(英文版)

CSTPCDEI
影响因子:0.818
ISSN:1004-9541
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