首页|Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane
Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane
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Effect of cobalt on the activity of nickel-based/magnesium-substituted hydroxyapatite catalysts for dry reforming of methane
The dry reforming of methane(DRM)reaction can directly convert methane(CH4)and carbon dioxide(CO2)into syngas(H2+CO),which is a promising method for achieving carbon neutralization.In this study,a series of 3Ni-xCo/Mg1HAP alloy catalysts with different ratio were synthesized by the copreci-pitation method,and the optimum Ni-Co ratio for the DRM reaction was studied.A series of charac-terization methods revealed that after Co was added,the formation of Ni-Co alloys increased the interactions between metals.However,an excess of Co inhibits the entry of Ni into the lattice of Mg1HAP,resulting in metal accumulation on the surface of the support.In addition,the introduction of Co im-proves the dispersion of Ni metal,which endows the catalyst with better catalytic activity and stability.Raman spectroscopy of the catalyst after the stability test showed that the addition of Co reduced the proportion of graphitic carbon,which was also the main reason for its improved stability.
MethaneCarbon dioxideHydroxyapatiteNickelCobalt
Tongming Su、Bo Gong、Xinling Xie、Xuan Luo、Zuzeng Qin、Hongbing Ji
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School of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China
Zhejiang Green Petrochemical and Light Hydrocarbon Transformation Research Institute,Zhejiang University of Technology,Hangzhou 310014,China
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