首页|SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS
SYNTHESIS OF POLYSILOXANE-SUPPORTED SELENAETHER PLATINUM COMPLEX AND ITS CATALYTIC PROPERTY FOR HYDROSILYLATION OF OLEFINS
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A new type of selenious polymer, silica-bound polybispropoxyethyl-selenidesilsesquioxane,and its platinum complex were synthesized from bis-allyloxyethyl selenide via hydrosilylation with triethoxysilane, followed by immobilized on fumed silica, and then reacting with potassium chloroplatinite under nitrogen atmosphere in acetone. It was found that the platinum complex can catalyze the hydrosilylation of olefins with triethoxysilane effectively. The effects of the nature of the substrate, the amount of complex used, and the reaction temperature on the catalytic activity were investigated.
NETL
NSTL
万方数据
维普
