高分子科学(英文版)2024,Vol.42Issue(6) :787-797.DOI:10.1007/s10118-024-3095-7

High Impact Polylactide Based on Organosilicon Nucleation Agent

Daria Paku?a Bogna Sztorch Eliza Romańczuk-Ruszuk Bogdan Marciniec Robert E.Przekop
高分子科学(英文版)2024,Vol.42Issue(6) :787-797.DOI:10.1007/s10118-024-3095-7

High Impact Polylactide Based on Organosilicon Nucleation Agent

Daria Paku?a 1Bogna Sztorch 2Eliza Romańczuk-Ruszuk 3Bogdan Marciniec 1Robert E.Przekop2
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作者信息

  • 1. Adam Mickiewia University in Poznań,Faculty of Chemistry,Uniwersytetu Poznańskiego 8,61-614 Poznań,Poland;Adam Mickiewicz University in Poznań,Centre for Advanced Technologies,Uniwersytetu Poznańskiego 10,61-614Poznań,Poland
  • 2. Adam Mickiewicz University in Poznań,Centre for Advanced Technologies,Uniwersytetu Poznańskiego 10,61-614Poznań,Poland
  • 3. Institute of Biomedical Engineering,Faculty of Mechanical Engineering,Bialystok University of Technology,Wiejska 45C,15-351 Bialystok Poland
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Abstract

Various sectors of the industry are searching for new materials with specific requirements,providing improved properties.The study presents novel composite materials based on polylactide that have been modified with the organosilicon compound,(3-thiopropyl)polysilsesquioxane(SSQ-SH).The SSQ-SH compound is a mixture of cage structures and not fully condensed random structures.The composite materials were obtained through injection moulding.The study includes a comprehensive characterization of the new materials that analyze their functional properties,such as rheology(MFR),mechanical strength(tensile strength,Charpy impact strength),and thermal properties.SEM microscopic photos were also taken to analyze the microstructure of the samples.The addition of a 5%by-weight organosilicon compound to polylactide resulted in a significant increase in MFR by 73.8%compared to the neat polymer.The greatest improvement in impact strength was achieved for the 5%SSQ-SH/PLA composite,increasing it by 32.0 kJ/m2 compared to PLA,which represents an increase of up to 187%.The con-ducted research confirms the possibility of modifying the properties of the polymer by employing organosilicon compounds.

Key words

Octa(3-thiopropyl)silsesquioxane/8SH-POSS/Polylactide(PLA)/Injection moulding/Composites

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基金项目

Smart Growth Operational Programme(POIR.04.02.00-00-D003/20-00)

European Funds(RPWP.01.01.00-30-0004/18)

Ministry of Science and Higher Education(21/529535/SPUB/SP/2022)

出版年

2024
高分子科学(英文版)
中国化学会 中国科学院化学研究所

高分子科学(英文版)

CSTPCDCSCD
影响因子:0.721
ISSN:0256-7679
参考文献量45
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