高分子科学(英文版)2024,Vol.42Issue(6) :815-825.DOI:10.1007/s10118-024-3089-5

Simultaneously Improved Curing,Mechanical,Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method

Chao-Ying Sun Hai-Jun Ji Li-Wei Li Hui Yang Xiao-Peng An Yi-Ping Chen Ming-Jian Han Can Jiang Li-Qun Zhang Peng Yu Run-Guo Wang
高分子科学(英文版)2024,Vol.42Issue(6) :815-825.DOI:10.1007/s10118-024-3089-5

Simultaneously Improved Curing,Mechanical,Antioxidative Properties and Reduced ZnO Loading of Silica Filled NR Composites by Incorporation of Low-cost Crude Carbon Dots via Conventional Melt-milling Method

Chao-Ying Sun 1Hai-Jun Ji 1Li-Wei Li 1Hui Yang 1Xiao-Peng An 1Yi-Ping Chen 1Ming-Jian Han 1Can Jiang 2Li-Qun Zhang 1Peng Yu 2Run-Guo Wang1
扫码查看

作者信息

  • 1. State Key Laboratory of Organic-Inorganic Composites,Beijing University of Chemical Technology,Beijing 100029,China
  • 2. School of Materials Science and Engineering,Wuhan Institute of Technology,Wuhan 430205,China
  • 折叠

Abstract

Rubbers or elastomers play an important role in hi-tech technology and civilian daily life because of their unique and strategical prop-erties.Generally,the rubber additives are essential components for rubbers'practical application.Nowadays,developing novel multifunctional additives has attracted increasing research attention.In this work,low-cost crude carbon dots(CCDs)were used as multifunctional additives for natural rubber/silica system(without any additional modification)through industrial compatible melt-mixing method.The results revealed that the CCDs could disperse well in the NR/silica system,and they could not only endow the rubber compound with excellent anti-aging capability due to CCDs'radical scavenging activity because of their plenty of nitrogen-containing species,but also improve the curing rate and mechanical performance of the rubber composite.Also,the CCDs could reduce the rolling resistance of the rubber composites(tano value at 7%strain of the rubber composite could be decreased by 34%),which is promising for the application of energy-saving tire industry.Lastly,the addition of CCDs could effectively reduce the ZnO dosage by at least 40%in the rubber composite without deteriorating its performance.Overall,this work pro-vides valuable guidance to develop novel cheap yet effective additives for the elastomer.

Key words

Natural rubber/Crude carbon dots/Antioxidant/ZnO reduction/Vulcanization

引用本文复制引用

基金项目

国家自然科学基金(52103065)

国家自然科学基金(51988102)

国家自然科学基金(52273003)

scientific research fund of Wuhan Institute of Technology(K2021044)

出版年

2024
高分子科学(英文版)
中国化学会 中国科学院化学研究所

高分子科学(英文版)

CSTPCDCSCD
影响因子:0.721
ISSN:0256-7679
参考文献量36
段落导航相关论文