Abstract
Rubbers or elastomers play an important role in hi-tech technology and civilian daily life because of their unique and strategical prop-erties.Generally,the rubber additives are essential components for rubbers'practical application.Nowadays,developing novel multifunctional additives has attracted increasing research attention.In this work,low-cost crude carbon dots(CCDs)were used as multifunctional additives for natural rubber/silica system(without any additional modification)through industrial compatible melt-mixing method.The results revealed that the CCDs could disperse well in the NR/silica system,and they could not only endow the rubber compound with excellent anti-aging capability due to CCDs'radical scavenging activity because of their plenty of nitrogen-containing species,but also improve the curing rate and mechanical performance of the rubber composite.Also,the CCDs could reduce the rolling resistance of the rubber composites(tano value at 7%strain of the rubber composite could be decreased by 34%),which is promising for the application of energy-saving tire industry.Lastly,the addition of CCDs could effectively reduce the ZnO dosage by at least 40%in the rubber composite without deteriorating its performance.Overall,this work pro-vides valuable guidance to develop novel cheap yet effective additives for the elastomer.
基金项目
国家自然科学基金(52103065)
国家自然科学基金(51988102)
国家自然科学基金(52273003)
scientific research fund of Wuhan Institute of Technology(K2021044)