首页|Counterion-Mediated Hydrogen Bonding Making Strong Polyelectrolytes pH-Responsive:Current Understanding and Perspectives
Counterion-Mediated Hydrogen Bonding Making Strong Polyelectrolytes pH-Responsive:Current Understanding and Perspectives
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
万方数据
维普
The counterion-mediated hydrogen bonding(CMHB)is related to the hydrogen bonding between bound counterions and polyelec-trolyte chains in polyelectrolyte systems,where the counterions can both electrostatically bind to the charged groups of polyelectrolyte chains and act as hydrogen bond donors or acceptors to form hydrogen bonds with the hydrogen bond sites associated with polyelectrolyte chains si-multaneously.A large number of literatures illustrate that strong polyelectrolytes(SPs)are insensitive to pH,which severely limmits the applica-tions of SPs as smart materials.However,our studies have demonstrated that the CMHB makes SPs pH-responsive.This perspective discusses the mechanism of pH responsiveness of SPs and the pH-tunable properties of SPs,based on the pH-controlled CMHB effect.The future research di-rections on the pH responsiveness of SPs are also discussed here.It is anticipated that the study of the pH responsiveness of SPs not only will pro-vide a new understanding of the fundamental properties of SPs,but also will greatly expand the applications of SPs in the field of smart materials.
Hefei National Research Center for Physical Sciences at the Microscale,Department of Chemical Physics,Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes,University of Science and Technology of China,Hefei230026,China
The Key Laboratory of Functional Molecular Solids,Ministry of Education,and Department of Materials Chemistry,School of Chemistry and Materials Science,Anhui Normal University,Wuhu 214002,China
National Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaNational Natural Science Foundation of ChinaFundamental Research Funds for the Central Universities
万方数据
维普
