首页|Catalyst-free and Reprocessable Aromatic Polydithiourethanes
Catalyst-free and Reprocessable Aromatic Polydithiourethanes
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
万方数据
维普
The incorporation of dynamic covalent bonds into thermosets facilitates the reprocessing of polymer networks,thereby meeting the sustainable requirements for polymer recycling.However,the mechanical properties of many materials often decline significantly upon repro-cessing due to side reactions caused by harsh processing conditions.In this work,we find that the aromatic dithiocarbamate bond can undergo dissociation under mild conditions without the need for a catalyst,enabling the efficient reprocessing of the corresponding polydithiourethane.As a consequence,the mechanical properties of the polydithiourethane can be largely preserved after reprocessing.The discovery of this dyna-mic chemistry is anticipated to broaden the potential for material design in dynamic covalent polymer networks.
ReprocessingPolydithiourethaneDynamic covalent bond
Bo Yang、Hai-Jun Feng、Tian-Tian Ni、Xiao-Rui Zhou、Tao Xie、Ning Zheng
展开 >
State Key Laboratory of Chemical Engineering,College of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310058,China
State Key Laboratory of Chemical Engineering,College of Chemical and Biological Engineering,Zhejiang University,Hangzhou310058,China
Department of Colorectal Surgery and Oncology,Key Laboratory of Cancer Prevention and Intervention,Ministry of Education,The Second Affiliated Hospital,Zhejiang University School of Medicine,Hangzhou 310009,China
National Natural Science Foundation of ChinaNational Natural Science Foundation of China
万方数据
维普
