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直流模式电流密度对铝锂合金微弧氧化膜性能的影响

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为了研究直流模式下电参数对铝锂合金微弧氧化成膜机理和膜层性能的影响,以2195铝锂合金为研究对象,在硅酸盐-磷酸盐碱性电解液体系中,以直流稳流模式在不同电流密度下制备了微弧氧化陶瓷膜.通过扫描电子显微镜(SEM)及其自带的能谱仪(EDS)、X射线衍射仪(XRD)分析了微弧氧化膜的表面和截面形貌、元素组成及物相组成.采用电化学工作站和摩擦磨损试验机分别测定了不同陶瓷膜的耐蚀性能和耐磨性能.结果表明:微弧氧化陶瓷膜中主要含O、Al、Si和P元素,膜层相组成主要为γ-Al2O3和少量α-Al2O3.在电流密度为4~16 A/dm2的范围内,随着电流密度的升高,膜层的耐蚀性和耐磨性都呈先升高后降低的趋势,电流密度为8 A/dm2时膜层的耐蚀性最好,自腐蚀电流密度为5.171 8×10-7 A/cm2,致密层电阻Rb值3.323×104 Ω·cm2.电流密度为8 A/dm2时膜层耐磨性最好,磨损机理为疲劳磨损和磨料磨损混合,磨损率为0.343 75×10-6 cm3/(N·m).
Effect of DC Mode Current Density on Properties of Micro-Arc Oxidation Film on Aluminum Lithium Alloy
In order to study the influence of electrical parameters on the film formation mechanism and film properties of aluminum-lithium alloy micro-arc oxidation in DC mode,2195 aluminum lithium alloy was used as the research object to prepare micro-arc oxidation ceramic film in a silicate phosphate alkaline electrolyte system under different current densities in a DC steady current mode.The surface and cross-sectional morphology,elemental composition and phase composition of micro-arc oxidation film were analyzed by scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS)and X-ray diffraction(XRD).The corrosion resistance and wear resistance of different ceramic film were measured by using an electrochemical workstation and a friction and wear tester.Results showed that the ceramic film mainly contained O,Al,Si,and P elements,and the phase composition of the film layer was mainly γ-Al2O3 and a small amount of α-Al2O3.In the range of cur-rent density 4~16 A/dm2,with the increase of current density,the corrosion resistance and wear resistance of the film layer first increased and then decreased.When the current density was 8 A/dm2,the as-prepared film possessed the optimal corrosion resistance,with the self-corro-sion current density of 5.171 8×10-7 A/cm2 and the dense layer resistance Rb of 3.323×104 Ω·cm2.When the current density was 8 A/dm2,the as-prepared film had the best wear resistance,and the wear mechanism was a mixture of fatigue wear and abrasive wear,with a wear rate of 0.343 75×10-6 cm 3/(N·m).

aluminum lithium alloyDC power supplymicro-arc oxidationabrasion resistancecorrosion resistance

吴鸿、冯长杰、王景、王赫男、李杰、辛丽、王福会

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沈阳航空航天大学材料科学与工程学院,辽宁沈阳 110136

中航光电科技股份有限公司,河南洛阳 471032

中国科学院金属研究所腐蚀与防护实验室,辽宁沈阳 110016

东北大学材料科学与工程学院,辽宁沈阳 110819

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铝锂合金 直流电源 微弧氧化 耐磨性 耐蚀性

辽宁省"兴辽英才计划"项目沈阳航空航天引进人才科研启动基金

XLYC200203119YB05

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(2)
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