首页|膜层厚度对6061铝合金黑色微弧氧化陶瓷膜层结构与性能的影响

膜层厚度对6061铝合金黑色微弧氧化陶瓷膜层结构与性能的影响

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为了明确膜层厚度对铝合金黑色微弧氧化陶瓷膜层的黑度、耐蚀性和硬度的影响规律,促进其实际应用,在硅酸盐-钒酸盐复合溶液体系中对6061铝合金进行微弧氧化处理,通过控制微弧氧化时间获得具有不同膜层厚度的铝合金黑色陶瓷膜层.利用测厚仪、粗糙度测量仪、SEM和EDS对黑色陶瓷膜层的表面结构、膜层成分和粗糙度等进行表征,并借助色差仪、维氏硬度计和电化学工作站等研究了膜层厚度对陶瓷膜层的黑度、显微硬度和耐蚀性的影响.结果表明:膜层厚度对黑色陶瓷膜层的表面形貌、粗糙度、显色特性、硬度和耐蚀性有较大影响.随着微弧氧化时间延长,膜层厚度增加,膜层表面更为粗糙,表层放电微孔数量减少,放电微孔孔径增大;当膜厚达到30.786 μm时,陶瓷膜层的放电微孔显著增大,孔径达到10 μm.随着膜层厚度增加,陶瓷膜层的黑度增加,显微硬度提高,但耐蚀性先增强后降低.当膜层厚度为20.781 μm时,陶瓷膜层的黑度和硬度较高,耐蚀性最好,其在3.5%NaCl溶液中的自腐蚀电流密度为1.093×10-6 A/cm2.
Effects of Coating Thickness on the Microstructure and Properties of Black Micro-Arc Oxidation Ceramic Coating on 6061 Aluminum Alloy
In order to reveal the influence law of coating thickness on the blackness,corrosion resistance and hardness of black micro-arc oxi-dation coatings on aluminum alloy for promoting their practical application,6061 aluminum alloy was treated by micro-arc oxidation in silicate-vanadate composite solution systems,and black ceramics coatings with different coating thickness on aluminum alloy were obtained through con-trolling micro-arc oxidation time.The surface structure,composition and roughness of the black ceramic coatings were characterized by thick-ness gauge,roughometer,SEM and EDS.Moreover,the effects of coating thickness on the blackness,microhardness and corrosion resistance of the black ceramic coatings were studied by using colorimeter,Vickers hardness tester and electro-chemistry workstation.Results showed that the coating thickness had great influence on the surface morphology,roughness,color features,microhardness and corrosion resistance.As the micro-arc oxidation time increased,the thickness of coatings increased,the surface of the coating became rougher,the number of discharge micropores on the surface declined,and the diameter of the discharge micropores increased.When the thickness increased to 30.786 μm,the size of discharge micropores increased significantly,reaching 10 μm.As the coating thickness increased,the blackness and microhardness of ceramic coatings improved,while the corrosion resistance increased firstly and then decreased.When the thickness reached 20.781 μm,the ceramic coating had higher microhardness and blackness,and showed the best corrosion resistance,with the self-corrosion current density of 1.093×10-6 A/cm2 in 3.5%(mass fraction)NaCl solution.

6061 aluminum alloyblack ceramic coatingcoating thicknesscorrosion resistancemicro-arc oxidation

沈文宁、王钰雯、李庚、葛延峰、胡鸣旸、汤玉斐

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西安理工大学材料科学与工程学院,陕西西安 710048

陕西省腐蚀与防护重点实验室,陕西西安 710048

6061铝合金 黑色陶瓷膜层 膜层厚度 耐蚀性 微弧氧化

陕西省自然科学基础研究计划面上项目陕西省教育厅重点实验室项目

2022JM-29418JS079

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(2)
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