首页|550NH耐候钢在3种典型大气环境中的初期腐蚀行为

550NH耐候钢在3种典型大气环境中的初期腐蚀行为

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针对广西壮族自治区不同区域的气候特征,选择城市、工业、海岸3种典型大气环境开展了耐候钢的初期腐蚀行为研究.分别采用大气暴露腐蚀试验和电化学测量试验对550 MPa强度级别的550NH耐候钢的耐腐蚀性进行评估.结果表明,550NH耐候钢在城市大气、工业、海岸3种环境中的腐蚀速率依次增加.550NH耐候钢在3地腐蚀6个月后的腐蚀产物主要为Fe3O4、α-FeOOH、γ-FeOOH.腐蚀产物层致密且无贯穿性裂纹主要归因于550NH耐候钢中Cu和Cr元素对裂纹和孔洞的修复作用.550NH在模拟海洋环境和模拟工业环境中的电化学阻抗谱随着腐蚀时间的延长逐渐由1个容抗弧转变为2个容抗弧组成.
Initial Corrosion Behavior of 550NH Weathering Steel in Three Typical Atmospheric Environments
According to the climatic characteristics of different regions in the Guangxi Zhuang autonomous region,the initial corrosion behavior of weathering resistant steel was studied in urban,industrial and coastal three typical atmospheric environments.The corrosion resistance of 550NH weathering steel with a strength level of 550 MPa was assessed through atmospheric exposure corrosion tests and electrochemical meas-urements.Results showed that the corrosion rate of 550NH weathering steel successively increased in urban,industrial and coastal environments.After six months of corrosion in three locations,the main corrosion products of 550NH weathering steel were identified as Fe3O4,α-FeOOH and γ-FeOOH.The corrosion product layer,being dense and devoid of penetrating cracks,was primarily attributed to the reparative effects of Cu and Cr elements on cracks and voids in 550NH weathering steel.With the extension of corrosion time,the electrochemical imped-ance spectra of 550NH in simulated marine and simulated industrial environments gradually transitioned from a single capacitive arc to a config-uration of two capacitive arcs.

550NH weathering steelatmospheric environmentinitial corrosion behaviorelectrochemical impedance

李宗强、韦素欣、王艳丽、张盛华

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广西柳州钢铁集团有限公司技术中心,广西柳州 545002

广西大学资源环境与材料学院,广西南宁 530004

特色金属材料与组合结构全寿命安全国家重点实验室,广西南宁 530004

广西大学化学化工学院,广西南宁 530004

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550NH耐候钢 大气环境 初期腐蚀行为 电化学阻抗

广西科级基地和人才专项广西柳州市科技计划项目

桂科AD192451452021AAD0101

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(3)
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