材料保护2024,Vol.57Issue(3) :179-183.DOI:10.16577/j.issn.1001-1560.2024.0071

热镀铝锌板黑线缺陷原因分析

Analysis of Black Line Defects in Hot-dip Al-Zn Sheets

许明文 孙朝勇 高士伟 李健 刘小华 姚莹
材料保护2024,Vol.57Issue(3) :179-183.DOI:10.16577/j.issn.1001-1560.2024.0071

热镀铝锌板黑线缺陷原因分析

Analysis of Black Line Defects in Hot-dip Al-Zn Sheets

许明文 1孙朝勇 1高士伟 1李健 2刘小华 2姚莹2
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作者信息

  • 1. 酒钢宏兴股份有限公司碳钢薄板厂,甘肃 嘉峪关 735100
  • 2. 酒钢宏兴股份有限公司钢铁研究院,甘肃 嘉峪关 735100
  • 折叠

摘要

为了查找薄规格热镀铝锌板黑线缺陷产生原因,采用ZEISS Merlin Compact场发射扫描电镜及其附带的OXFORD X-max N型能谱仪等分析技术对热镀铝锌钢板黑线缺陷表面、截面以及腐蚀去掉镀层后的钢铁基板表面进行了微观形貌观察和化学成分分析.结果表明:热镀铝锌钢板上表面黑线缺陷是由于钢铁基板划伤致使钝化膜较厚所致;热镀铝锌钢板下表面黑线缺陷是由于下表面镀层发生凹陷微变形致使钝化膜较厚所致.热镀铝锌钢板表面划伤以及镀层凹陷造成与周围其他位置对光的反射不同,形成了视觉上的黑线缺陷.

Abstract

In order to identify the causes of black line defects in thin specification hot-dip Al-Zn sheets,a ZEISS Merlin Compact field emission scanning electron microscope(SEM)and an attached OXFORD X-max N type energy spectrometer were utilized to analyze the surface and cross-section of black line defects in hot-dip Al-Zn steel plates,as well as the microstructure observation and chemical composition of the steel substrate surface after corrosion and removal of the coating.Analysis was also conducted on the steel substrate surface after the coating had been removed by corrosion.Results showed that the black line defects on the upper surface of the hot-dip Al-Zn steel sheet were caused by a thicker pas-sive film due to scratches on the steel substrate.On the lower surface of the hot-dip Al-Zn sheet,the black line defects were attributed to a thicker passive film resulting from concave micro-deformations of the lower surface coating.Scratches on the surface and depressions of the coating of the Al-Zn steel sheet were found to cause different reflections of light from the rest of the surrounding area,forming a visually perceived black line defect.

关键词

热镀铝锌板/黑线/缺陷/钝化膜

Key words

hot-dip Al-Zn sheet/the black line/defect/passive film

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基金项目

甘肃省科技重大专项(22ZD6GB019)

出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
参考文献量11
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