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石墨烯层数对分散性和摩擦学性能的影响

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为了提高传动油基础油的摩擦学性能并探究石墨烯层数对其的影响,选用了不同层数的石墨烯纳米片和纳米石墨(NG)作为传动油基础油的润滑添加剂,使用UMT-3往复摩擦试验机测试了不同层数石墨烯以及纳米石墨传动油基础油的润滑特性.结果显示:不同层数的石墨烯在传动油基础油中的分散稳定性不同.其中,单层石墨烯由于其表面积大,层间作用力较弱,油分子可以充分填充石墨烯层间发生位阻效应,因而拥有最优异的分散稳定性.此外,不同层数的石墨烯以及NG作为传动油润滑添加剂都可以提高传动油基础油的润滑特性.其中,单层石墨烯(SGN)传动油展现出最佳的摩擦学性能,其磨损量与基础油相比减少了 98%.另外,对石墨烯以及NG传动油润滑的磨损表面的Raman测试中检测出明显的石墨烯峰,说明石墨烯以及NG在摩擦区域的吸附形成了致密的摩擦膜从而降低了摩擦系数和磨损率.对SGN传动油的摩擦产物进行收集并观察,有力地揭示了其润滑机理.SGN优异的摩擦学性能主要归因于其优异的分散稳定性以及剪切作用下发生的结构有序化转变.
The Effect of Graphene Layer Number on Dispersibility and Tribological Performance
In order to improve the tribological performance of transmission oil base oil and explore the influence of graphene layers on it,the graphene nanosheets with different layers and nano graphite(NG)were selected as lubrication additives for transmission oil base oil,and the lubrication characteristics of different layers of graphene and nano graphite transmission oil base oils were tested by UMT-3 reciprocating friction tester.Results showed that the dispersion stability of graphene with different layers in transmission oil base oil was different.Among them,single-layer graphene had the best dispersion stability due to its large surface area and weak interlayer forces,and oil molecules could fully fill the graphene interlayer and cause steric hindrance effects,which endowed it with the best dispersion stability.Moreover,all graphene with different layers and NG as lubricating additives for transmission oil could improve the lubrication characteristics of the transmission oil base oil.Therein,single-layer graphene(SGN)transmission oil exhibited the best tribological performance,with a 98%reduction in wear amount compared to base oil.In addition,the significant graphene peaks were detected in Raman tests on the worn surfaces lubricated with graphene and NG transmission oil,indicating that the adsorption of graphene and NG in the friction area formed a dense friction film,thereby reducing the friction coefficient and wear rate.Collecting and observing the friction products of SGN transmission oil effectively revealed its lubrication mechanism.Besides,the excellent tribological performance of SGN was mainly attributed to its excellent dispersion stability and the structural ordering transformation that occurred under shear action.

graphenenumber of layerstribological propertiesdispersibilityordering transformation

张春风、张晓军、张伟、赵壮、樊小强

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山西潞安太行润滑科技股份有限公司,山西长治 046011

西南交通大学材料科学与工程学院材料先进技术教育部重点实验室,四川成都 610031

石墨烯 层数 摩擦学性能 分散性 有序化转变

国家自然科学基金面上项目

52075458

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(4)
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