首页|联合添加微量Sc、Zr元素对B4C/7075Al复合材料力学性能和腐蚀行为的影响

联合添加微量Sc、Zr元素对B4C/7075Al复合材料力学性能和腐蚀行为的影响

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限制高强度B4C/Al复合材料工程应用的关键为腐蚀问题,添加微量合金元素是提高其耐蚀性的有效措施.采用压力浸渗法制备了 B4C/7075和添加微量Sc、Zr元素的B4C/7075-0.15Sc-0.35Zr复合材料,利用扫描电镜、透射电镜、弯曲性能测试、拉伸性能测试、中性盐雾试验和电化学测试对比研究了联合添加Sc和Zr元素对B4C/7075Al复合材料的显微组织、力学性能和腐蚀行为的影响.结果表明:添加Sc和Zr元素后,复合材料的抗弯曲强度和抗拉强度升高,腐蚀速率降低,腐蚀电流密度(Jcorr)下降,耐蚀性增强,这是因为添加Sc和Zr元素后,复合材料的晶界析出相细小且不连续分布,无析出带(PFZ)消失.
Effect of Combined Addition of Trace Sc and Zr Elements on Mechanical Properties and Corrosion Behavior of B4C/7075Al Composite
The key to restrict the engineering application of high-strength B4C/Al composites is corrosion,and adding trace alloying elements is an effective measure to improve corrosion resistance.In this work,the B4C/7075 and B4C/7075-0.15Sc-0.35Zr composite containing trace Sc and Zr elements were prepared by pressure infiltration.The influence of combined addition of Sc and Zr on microstructure,mechanical properties and corrosion behavior of B4C/7075 composites was investigated by using scanning electron microscopy,transmission electron mi-croscopy,bending performance testing,tensile performance testing,neutral salt spray testing and electrochemical testing.Results showed that adding Sc and Zr elements to B4C/7075 composites,the higher bending strength and tensile strength values were obtained in B4C/7075-0.15Sc-0.35Zr.In addition,the corrosion rate and the corrosion current(Jcorr)decreased,indicating that the corrosion resistance of B4C/Al composite increased,which might be caused by that the grain boundary precipitates in the composite material were small and discontinuous after adding Sc and Zr elements,and the precipitate free zone(PFZ)disappeared.

B4C/7075 compositeScZrmechanical propertiescorrosion behaviorPFZ

韩慧敏、姜龙涛、晁振龙、韩秉卓、王春雨

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哈尔滨工业大学材料科学与工程学院,黑龙江哈尔滨 150001

哈尔滨工业大学(威海)材料科学与工程学院,山东威海 264209

B4C/7075复合材料 Sc Zr 力学性能 腐蚀行为 无析出带

国家自然科学基金资助项目

52101172

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(4)
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