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石化加氢装置典型腐蚀与防护

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通过典型腐蚀案例和腐蚀介质分布分析,总结了石化加氢装置的腐蚀规律,主要腐蚀类型有:反应流出物系统NH4Cl结晶及垢下腐蚀、NH4HS冲刷腐蚀、HCl露点腐蚀、循环氢脱硫塔和汽提塔湿H2S腐蚀等.明确了加氢装置各类典型腐蚀机理的关键影响因素,并针对性地从设备及管线选材、操作优化和腐蚀监检测等方面提出了腐蚀防护措施,对降低设备、管线腐蚀风险,保证加氢装置长周期安全运行具有很好的指导意义.
Typical Corrosion and Protection of Petrochemical Hydrogenation Unit
Through the analysis of typical corrosion cases and the distribution of corrosion media,the corrosion patterns of petrochemical hydro-genation units were summarized.The main types of corrosion were identified as:crystallization of NH4Cl and under-deposit corrosion in the re-action effluent system,erosion corrosion by NH4HS,dew point corrosion by HCl and wet H2S corrosion in the circulating hydrogen desulfuriza-tion tower and stripping tower.The key influencing factors of various typical corrosion mechanisms in hydrogenation units were identified,and targeted corrosion protection measures were proposed,encompassing the selection of equipment and pipeline materials,optimization of operation and enhancement of corrosion monitoring and detection.This paper offered significant guidance for reducing the risk of equipment and pipeline corrosion and ensuring the long-term safe operation of hydrogenation units.

hydrogenation deviceunder-deposit corrosionNH4Cl crystallizationNH4HS erosion corrosionwet H2S corrosioncorrosion protection

陈文武

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中石化安全工程研究院有限公司化学品安全全国重点实验室,山东青岛 266100

加氢装置 垢下腐蚀 NH4Cl结晶 NH4HS冲刷腐蚀 湿H2S腐蚀 腐蚀防护

中国石化科研项目

CLY23049

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(4)
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