材料保护2024,Vol.57Issue(6) :1-7.DOI:10.16577/j.issn.1001-1560.2024.0120

镁合金表面沉积Al-Al2O3/AT13复合涂层及其耐磨耐蚀性能研究

Study on the Deposition of Al-Al2O3/AT13 Composite Coating on the Surface of Magnesium Alloy and Its Wear and Corrosion Resistance Properties

熊凡奇 揭晓华 卢静 孙澄川 邓碧欣
材料保护2024,Vol.57Issue(6) :1-7.DOI:10.16577/j.issn.1001-1560.2024.0120

镁合金表面沉积Al-Al2O3/AT13复合涂层及其耐磨耐蚀性能研究

Study on the Deposition of Al-Al2O3/AT13 Composite Coating on the Surface of Magnesium Alloy and Its Wear and Corrosion Resistance Properties

熊凡奇 1揭晓华 1卢静 2孙澄川 2邓碧欣2
扫码查看

作者信息

  • 1. 广东工业大学材料与能源学院,广东 广州 510006
  • 2. 季华实验室,广东 佛山 528255
  • 折叠

摘要

为了提高镁合金的耐磨耐蚀性并拓展其应用领域,首先采用冷喷涂法在镁合金基体表面沉积一层Al-20%(质量分数)Al2O3(缩写:Al-Al2O3)涂层作为复合涂层过渡层,然后采用大气等离子喷涂法在其表面制备Al2O3-13%(质量分数)TiO2(缩写:AT13)面层,从而获得Al-Al2O3/AT13复合涂层.采用扫描电镜分析了过渡层与面层的表面与截面形貌,借助显微硬度仪和万能试验机测定了复合涂层的显微硬度与结合强度,采用摩擦磨损仪测定了复合涂层的摩擦系数与磨损率,利用动电位扫描技术研究复合涂层在3.5%(质量分数)NaCl溶液中的腐蚀行为.结果表明:Al-Al2O3过渡层与AT13面层的显微硬度分别为(42.3±13.7)HV0.1、(838.8±87.6)HV0.1,Al-Al2O3/AT13复合涂层结合强度为31.2 MPa;在40 N载荷和10 min的磨损条件下,复合涂层的稳定摩擦系数与磨损率为0.74、5.94×10-5mm3/(N·m),与镁合金基体[1.89×10-4 mm3/(N·m)]相比,磨损率减少了68.6%;在经过30 min的3.5%NaCl溶液浸泡后,复合涂层的腐蚀电位为-927 mV,腐蚀电流密度为1.81×10-5 A/cm2,与镁合金基体相比,腐蚀电位增大了742 mV,腐蚀电流密度下降了1个数量级.

Abstract

In order to improve the wear and corrosion resistances of magnesium alloys and broaden their application areas,a layer of Al-20%(mass fraction) Al2O3(abbreviated as Al-Al2O3) coating was firstly deposited on the surface of the magnesium alloy substrate by cold spraying method as the transition layer of the composite coating,and then an Al2O3-13%(mass fraction) TiO2(abbreviated as AT13) surface layer was prepared on its surface by atmospheric plasma spraying method,thereby obtaining an Al-Al2O3/AT13 composite coating. Subsequently,the surface and cross-sectional morphology of the transition layer and surface layer were analyzed by scanning electron microscopy,and the micro-hardness and bonding strength of the composite coating were measured using a microhardness tester and a universal testing machine. Moreover,the friction coefficient and wear rate of the composite coating were measured by a friction and wear tester,and the corrosion behavior of the composite coating in a 3.5%(mass fraction) NaCl solution was investigated through dynamic potential scanning technology. Results showed that the microhardness of the Al-Al2O3 transition layer and the AT13 surface layer were (42.3±13.7) HV0.1 and (838.8±87.6) HV0.1,respective-ly,and the bonding strength of the Al-Al2O3/AT13 composite coating was 31.2 MPa. Additionally,the stable friction coefficient and wear rate of the composite coating were 0.74 and 5.94×10-5 mm3/(N·m) under a load of 40 N and a wear condition of 10 min,and compared with the magnesium alloy substrate[1.89×10-4 mm3/(N·m)],the wear rate was reduced by 68.6%. After being immersed in a 3.5%NaCl solution for 30 min,the corrosion potential of the composite coating was-927 mV,and the corrosion current density was 1.81×10-5 A/cm2. Compared to the magnesium alloy substrate,the corrosion potential increased by 742 mV,and the corrosion current density decreased by an order of magnitude.

关键词

冷喷涂/等离子喷涂/镁合金/复合涂层/耐磨性/耐蚀性

Key words

cold spraying/plasma spraying/magnesium alloy/composite coating/wear resistance/corrosion resistance

引用本文复制引用

基金项目

国家重点研发计划"先进结构与复合材料"重点专项(2021YFB3702003)

国家重点研发计划"先进结构与复合材料"重点专项(2021YFB3702003)

季华实验室自主立项项目(X190391TJ190)

出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCDCSCD
影响因子:1.129
ISSN:1001-1560
参考文献量4
段落导航相关论文