首页|Al2O3+TiO2复合颗粒对激光熔覆Inconel 718基润滑涂层显微组织及高温磨损行为的影响研究

Al2O3+TiO2复合颗粒对激光熔覆Inconel 718基润滑涂层显微组织及高温磨损行为的影响研究

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针对Inconel 718镍基合金易在宽温域条件下发生磨损失效的问题,选用2种不同含量Al2O3+TiO2颗粒(10%,20%,质量分数)作为陶瓷增强相,利用激光熔覆技术制备了2种Inconel 718-MoS2-Al2O3-TiO2高温耐磨润滑复合涂层,系统地研究了复合涂层的微观组织、力学性能和摩擦学性能,以为其在摩擦学领域的应用提供数据支持.结果表明:复合涂层主要由γ-Ni固溶体、γ'-Ni3(Ti,Al)金属间化合物、Ti3O5和Al2O3陶瓷增强相以及MoS2润滑相共同组成.当TiO2和Al2O3的含量达到20%时,更高含量的Ti3O5和Al2O3有利于涂层高的硬度和弹性模量,显微硬度最高可达455 HV0.3,然而会造成Ti3O5和Al2O3物相晶粒粗大,不利于弹性模量和抗塑性变形能力的提升.当摩擦温度为室温~200℃时,TiO2和Al2O3含量为10%的复合涂层的摩擦系数和磨损率显著升高并达到了最大值,磨损机理主要为磨粒磨损和片层脱落;随着温度升高到400℃,涂层磨痕表面能够形成连续氧化膜促使磨损率显著降低.当温度达到600~800℃,2种复合涂层摩擦表面都能形成连续光滑的氧化膜起到润滑效应,使摩擦学性能得到显著改善,特别是磨损率相比于Inconel 718合金涂层降低1个数量级.当TiO2和Al2O3含量达到20%时,复合涂层在中高温下有更优异的摩擦学性能.通过对比发现Inconel 718-MoS2-Al2O3-TiO2复合涂层相比于Inconel 718合金涂层在室温~800℃表现出更优异的摩擦学性能.
Effects of Al2O3-TiO2 Composite Particles on the Microstructure and High-Temperature Wear Behavior of Laser Cladding Inconel 718-Based Lubricant Coatings
To address the issue of wear failure in Inconel 718 nickel-based alloy under wide temperature conditions,two different contents of Al2O3+TiO2 particles (10%,20%,mass fraction) were selected as ceramic reinforcement phases. Two types of Inconel 718-MoS2-Al2O3-TiO2 high-temperature wear-resistant lubricating composite coatings were prepared using laser cladding technology. The microstructure,mechanical properties and tribological behavior of the composite coatings were systematically investigated to provide data support for their application in the field of tribology. Results showed that the composite coatings were primarily composed of γ-Ni solid solution,γ'-Ni3(Ti,Al) intermetallic compounds,Ti3O5 and Al2O3 ceramic reinforcement phases,as well as MoS2 lubricating phase. When the content of TiO2 and Al2O3 reached 20%,higher levels of Ti3O5 and Al2O3 contributed to increased hardness and elastic modulus of the coatings,with a maximum microhardness of up to 455 HV0.3 . However,this led to coarser grains of Ti3O5 and Al2O3 phases,which were unfavorable for enhancing the elastic modulus and resistance to plastic deformation. At friction temperatures ranging from room temperature to 200℃,the friction coefficient and wear rate of the composite coatings with 10%TiO2 and Al2O3 content significantly increased,reaching maximum values. Wear mechanisms were mainly at-tributed to abrasive wear and delamination. As the temperature increased to 400℃,the formation of a continuous oxide film on the coating ab-rasion surface led to a significant reduction in wear rate. When the temperature reached 600~800℃,both types of composite coatings formed continuous smooth oxide films on the friction surfaces,exhibiting lubricating effects and significantly improving tribological performance,espe-cially with a reduction in wear rate by one order of magnitude compared to Inconel 718 alloy coatings. When the content of TiO2 and Al2O3 reached 20%,the composite coatings demonstrated superior tribological performance at intermediate to high temperatures. A comparative analy-sis revealed that the Inconel 718-MoS2-Al2O3-TiO2 composite coatings exhibited better tribological performance than Inconel 718 alloy coatings across temperatures ranging from room temperature to 800 ℃.

laser claddingnickel-based composite coatingshigh temperature wear-resistantself-lubrication at wide temperature range

张普、曹四龙

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内蒙古工业大学材料科学与工程学院,内蒙古 呼和浩特 010051

激光熔覆 镍基复合涂层 高温耐磨损 宽温域自润滑

内蒙古自然科学基金内蒙古自治区直属高校基本科研业务费项

2022QN05025JY20220123

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(6)
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