材料保护2024,Vol.57Issue(6) :52-58.DOI:10.16577/j.issn.1001-1560.2024.0126

CeO2-ZrO2-Al2O3/丙烯酸防腐涂料的制备及性能研究

Preparation and Performance Research of CeO2-ZrO2-Al2O3/Acrylic Anti-Corrosion Coatings

汪秀 李乾坤 王继虎 李辉 吴远东 温绍国 梅大江
材料保护2024,Vol.57Issue(6) :52-58.DOI:10.16577/j.issn.1001-1560.2024.0126

CeO2-ZrO2-Al2O3/丙烯酸防腐涂料的制备及性能研究

Preparation and Performance Research of CeO2-ZrO2-Al2O3/Acrylic Anti-Corrosion Coatings

汪秀 1李乾坤 2王继虎 2李辉 2吴远东 2温绍国 2梅大江2
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作者信息

  • 1. 桐城师范高等专科学校,安徽 桐城 231400
  • 2. 上海工程技术大学化学化工学院,上海 201620
  • 折叠

摘要

为探究填充不同质量的无机填料CeO2-ZrO2-Al2O3(CZA)粉体对丙烯酸涂料防腐性能及各项力学性能的影响,采用共沉淀法经过干燥煅烧合成了CZA粉体样品,将得到的CZA粉末配以市场上常用的分散剂、消泡剂等助剂在丙烯酸树脂中充分分散,并以刮涂的处理方法在经过处理的铁板上制备不同质量分数的丙烯酸防腐涂层.采用XRD、SEM和EDS对CZA粉体样品进行物相分析,利用力学性能测试和电化学防腐性能测试对涂层附着力、硬度、粗糙度、弯折性能、耐磨性、拉伸强度、断裂伸长率、防腐性能等特性进行评估.结果表明,制备得到的CZA粉体为固溶体,呈现四面体结构,添加CZA粉末后,涂层硬度提高,由HB上升至1H,弯曲性能皆为1T,耐磨性能得到提高,附着力皆为1级.与没有添加CZA的丙烯酸防腐涂层相比,CZA增强了涂层的防腐性能,当填料添加质量分数为10%时,涂层防腐性能最佳.该丙烯酸类防腐涂料具有一定的防腐性能,能够有效防止腐蚀介质对材料的腐蚀,未来在防腐领域具有一定的应用前景.

Abstract

In order to investigate the effect of filling different masses of inorganic filler CeO2-ZrO2-Al2O3(CZA) powder on the anticorrosive and mechanical properties of acrylic coatings,CZA powder samples were synthesized by drying and calcination using the co-precipitation meth-od. The obtained CZA powder was fully dispersed in acrylic resin with commonly used dispersants,defoamers and other additives available in the market,and the acrylic anticorrosive coatings with different mass fractions were prepared on treated iron plates by the scraping method.Meanwhile,the XRD,SEM and EDS methods were used to analyze the physical phase of the CZA powder samples,and the mechanical proper-ty tests and electrochemical anticorrosion property tests were utilized to evaluate the characteristics of the coatings,such as adhesion,hardness,roughness,bending performance,wear resistance,tensile strength,elongation at break and anticorrosion performance. Results showed that the as-prepared CZA powders were solid solutions and showed a tetrahedral structure. After adding CZA powder,the hardness of the coating in-creased from HB to 1H,the bending properties were all 1T,wear resistance was improved,and adhesion was all grade 1. CZA increased the anticorrosive properties of the coatings compared to acrylic anticorrosive coatings without CZA addition,and the best anticorrosive properties of the coatings were obtained when the mass fraction of filler addition was 10%. Overall,the acrylic anticorrosive coating had certain anticorrosive properties and could effectively prevent the corrosion of corrosive media on the material,which presented certain application prospects in the field of anti-corrosion in the future.

关键词

CZA粉体/丙烯酸树脂/涂层/粗糙度/防腐性能

Key words

CZA powder/acrylic resin/coating/roughness/anti-corrosion properties

引用本文复制引用

基金项目

2021年安徽省教育厅自然科学重点研究项目(KJ2021A1300201)

2023年安徽省中青年教师培养行动项目——优秀青年教师培育一般项目(YQYB2023124)

出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCDCSCD
影响因子:1.129
ISSN:1001-1560
参考文献量3
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