材料保护2024,Vol.57Issue(6) :81-87.DOI:10.16577/j.issn.1001-1560.2024.0130

316L不锈钢在Cl-与SO42-协同作用下的腐蚀行为研究

Synergistic Effect of Cl-and SO42-on the Corrosion Behavior of 316L Stainless Steel

赵恒瑞 侯政煜 杨海燕 梁守才 程龙生 王丹 谢飞
材料保护2024,Vol.57Issue(6) :81-87.DOI:10.16577/j.issn.1001-1560.2024.0130

316L不锈钢在Cl-与SO42-协同作用下的腐蚀行为研究

Synergistic Effect of Cl-and SO42-on the Corrosion Behavior of 316L Stainless Steel

赵恒瑞 1侯政煜 2杨海燕 2梁守才 2程龙生 3王丹 4谢飞4
扫码查看

作者信息

  • 1. 辽宁石油化工大学石油天然气工程学院,辽宁 抚顺 113001;中国石油大庆炼化公司,黑龙江 大庆 163712
  • 2. 中石油辽河油田油气集输公司,辽宁 盘锦 124010
  • 3. 浙石化新奥 (舟山) 燃气有限公司,浙江 舟山 316100
  • 4. 辽宁石油化工大学石油天然气工程学院,辽宁 抚顺 113001
  • 折叠

摘要

为了降低腐蚀对海洋油气管道正常运行的危害,利用电化学试验中的交流阻抗技术以及循化极化技术研究了模拟南海海洋环境中Cl-与SO42-的协同作用对316L不锈钢腐蚀行为的影响,并结合扫描电子显微镜(SEM)对316L不锈钢表面的腐蚀形貌进行表征.结果表明,当SO42-含量恒定时,Cl-含量的升高会使容抗弧半径、极化电阻Rp以及点蚀电位Eb均降低,当Cl-含量从0升至50 g/L时,316L不锈钢表面出现了明显的腐蚀情况.当Cl-含量恒定时,SO42-含量的升高会使容抗弧半径、Rp以及Eb值均减小,同时试件表面的腐蚀坑直径扩大,深度出现逐渐加深的情况.

Abstract

In order to reduce the harm caused by corrosion to the normal operation of offshore oil and gas pipelines,the effects of the synergis-tic effect of Cl-and SO42-on the corrosion behavior of 316L stainless steel in the simulated South China Sea marine environment were investiga-ted through the AC impedance technique and the cyclic polarization technique in electrochemical tests,and the corrosion morphology of 316L stainless steel surface was characterized by scanning electron microscopy (SEM) . Results showed that when the SO42-content was constant,an increase in Cl-content could reduce the capacitive arc radius,polarization resistance Rp and pitting potential Eb . As the Cl-content increased from 0 to 50 g/L,significant corrosion was observed on the surface of 316L stainless steel. When the Cl-content was constant,an increase in SO42-content reduced the capacitive arc radius,Rp and Eb values. At the same time,the diameter of the corrosion pit on the surface of the specimen expanded,and the depth gradually deepened.

关键词

316L不锈钢/海洋环境/Cl-/SO42-/协同作用/循环极化

Key words

316L stainless steel/marine environment/Cl-/SO42-/synergistic effect/cyclic polarization

引用本文复制引用

基金项目

辽宁省自然科学基金(2022-MS-362)

出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCDCSCD
影响因子:1.129
ISSN:1001-1560
参考文献量7
段落导航相关论文