首页|316L不锈钢在Cl-与SO42-协同作用下的腐蚀行为研究

316L不锈钢在Cl-与SO42-协同作用下的腐蚀行为研究

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为了降低腐蚀对海洋油气管道正常运行的危害,利用电化学试验中的交流阻抗技术以及循化极化技术研究了模拟南海海洋环境中Cl-与SO42-的协同作用对316L不锈钢腐蚀行为的影响,并结合扫描电子显微镜(SEM)对316L不锈钢表面的腐蚀形貌进行表征.结果表明,当SO42-含量恒定时,Cl-含量的升高会使容抗弧半径、极化电阻Rp以及点蚀电位Eb均降低,当Cl-含量从0升至50 g/L时,316L不锈钢表面出现了明显的腐蚀情况.当Cl-含量恒定时,SO42-含量的升高会使容抗弧半径、Rp以及Eb值均减小,同时试件表面的腐蚀坑直径扩大,深度出现逐渐加深的情况.
Synergistic Effect of Cl-and SO42-on the Corrosion Behavior of 316L Stainless Steel
In order to reduce the harm caused by corrosion to the normal operation of offshore oil and gas pipelines,the effects of the synergis-tic effect of Cl-and SO42-on the corrosion behavior of 316L stainless steel in the simulated South China Sea marine environment were investiga-ted through the AC impedance technique and the cyclic polarization technique in electrochemical tests,and the corrosion morphology of 316L stainless steel surface was characterized by scanning electron microscopy (SEM) . Results showed that when the SO42-content was constant,an increase in Cl-content could reduce the capacitive arc radius,polarization resistance Rp and pitting potential Eb . As the Cl-content increased from 0 to 50 g/L,significant corrosion was observed on the surface of 316L stainless steel. When the Cl-content was constant,an increase in SO42-content reduced the capacitive arc radius,Rp and Eb values. At the same time,the diameter of the corrosion pit on the surface of the specimen expanded,and the depth gradually deepened.

316L stainless steelmarine environmentCl-SO42-synergistic effectcyclic polarization

赵恒瑞、侯政煜、杨海燕、梁守才、程龙生、王丹、谢飞

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辽宁石油化工大学石油天然气工程学院,辽宁 抚顺 113001

中国石油大庆炼化公司,黑龙江 大庆 163712

中石油辽河油田油气集输公司,辽宁 盘锦 124010

浙石化新奥 (舟山) 燃气有限公司,浙江 舟山 316100

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316L不锈钢 海洋环境 Cl- SO42- 协同作用 循环极化

辽宁省自然科学基金

2022-MS-362

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(6)
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