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大牛地气田某集输管道腐蚀机理研究

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为明确大牛地气田某集输管道腐蚀问题,针对现场的腐蚀挂片与腐蚀管段采用腐蚀速率测试、微观形貌观察及腐蚀产物分析等方法,研究了该集输管道在H2S/CO2共存环境下的腐蚀机理,为制定相应腐蚀防护措施提供基础.研究表明:腐蚀挂片平均腐蚀速率为0.0923 mm/a,高于行业标准要求的0.0760 mm/a,局部腐蚀速率约为0.1570 mm/a,孔蚀系数约为2.7,腐蚀管段试片蚀坑最大深度为88μm;腐蚀产物膜结构疏松,保护性能较差;腐蚀产物中C、O和S元素的含量远高于20碳钢的化学成分,腐蚀产物主要由FeCO3、FeS、Fe2O3组成,说明集输管道所发生的腐蚀主要是由CO2和H2S遇潮湿环境后导致的.
Study on the Corrosion Mechanism of a Gathering Pipeline in Daniudi Gas Field
To clarify the corrosion problem of a certain gathering and transportation pipeline in the Daniudi gas field,corrosion rate tests,micro-morphology observations and corrosion product analyses were conducted on the corrosion coupons and corroded pipe sections on-site. The corrosion mechanism of the gathering pipeline in an H2S/CO2 coexistence environment was studied to provide a basis for formulating corresponding corrosion protection measures. Results showed that the average corrosion rate of the corrosion coupon was 0.0923 mm/a,which was higher than the 0.0760 mm/a required by the industry standard. The local corrosion rate was 0.1570 mm/a,the pitting corrosion coeffi-cient was 2.7,and the maximum depth of the corrosion pit on the test piece of the corroded pipe section was 88μm. The corrosion product film had a loose structure and poor protection performance. The corrosion products mainly contained C,O and S elements,which were much higher than the chemical composition of 20 carbon steel. The corrosion products were mainly composed of FeCO3,FeS and Fe2O3,indicating that the corrosion of the gathering pipeline was mainly caused by CO2 and H2S when encountering humid environments.

Daniudi gas fieldgathering pipelineH2S/CO2 coexistencecorrosion mechanism

周军、彭思洲、刘诗桃、韩杰林、熊梓豪、梁光川

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西南石油大学石油与天然气工程学院,四川 成都 610500

中国石油化工股份有限公司华北油气分公司采气一厂,陕西 榆林 719000

大牛地气田 集输管道 H2S/CO2共存 腐蚀机理

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(6)
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