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闪蒸换热器腐蚀失效机理与完整性管理对策研究

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某处理站闪蒸换热器管束腐蚀穿孔失效频发,为此对管束外部介质及管束表面腐蚀产物进行了分析测试.结果表明,壳程中的凝析油介质含少量的水,水质成分中含有高浓度氯离子、钙离子,同时含有HCO-3.在管束表面形成了黑色的垢层,垢下具有成片的腐蚀坑,局部腐蚀严重.通过对腐蚀产物的形貌、元素和化合物的分析,腐蚀产物主要为FeCO3,并在管束表面形成了富氯层,因此建立了垢下协同HCO-3,Cl-腐蚀机理.最后,建立了以失效控制为核心的闪蒸换热器完整性管理流程,形成了具有针对性的风险评价方法和失效控制措施,为处理站安全生产提供了保障.
Study on the Corrosion Failure Mechanism and Integrity Management Strategies of Flash Evaporation Heat Exchanger
The corrosion and perforation failure of the flash evaporation heat exchanger tube bundle in a certain treatment station occurred fre-quently. Therefore,a composition test was conducted on the external media and corrosion products on the surface of the tube bundle. Results showed that the condensate oil medium in the shell side contained a small amount of water,and there were the high concentrations of Cl-,Ca2+and HCO3-in the water quality components. A black scale layer was formed on the surface of the tube bundle,with patches of corrosion pits under the scale,indicating severe local corrosion. Based on the analysis of the morphology,elements and compounds of the corrosion products,it was found that the corrosion products were mainly composed of FeCO3,and a chlorine-rich layer was formed on the surface of the tube bun-dle. Therefore,a corrosion mechanism of synergistic HCO3-and Cl-under scale was established. Finally,an integrity management process for flash evaporation heat exchangers with failure control as the core was established,and targeted risk assessment methods and failure control measures were formed to provide assurance for the safe production of the treatment station.

heat exchangercorrosionfailurecontrol

王传平、吕小明、张洪杰、刘俊麟、彭万里、刘明明、钟萧林、佟旭波

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中国石油新疆油田采气一厂,新疆 克拉玛依 834000

换热器 腐蚀 失效 控制

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(6)
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