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供水管道中球墨铸铁与H62黄铜的电偶腐蚀行为研究

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为探讨自来水管网中球墨铸铁与H62黄铜供水管连接存在的电偶腐蚀问题,在模拟酸性工业大气腐蚀条件下,采用电化学噪声(EN)测试、能谱仪、扫描电镜考察了不同温度(0、25、40℃)、不同阴阳极面积比(Sc∶Sa=1∶1、2∶1、4∶1)时球墨铸铁/H62黄铜电极的电偶腐蚀电流、腐蚀形貌及腐蚀产物成分情况.结果表明:球墨铸铁/H62黄铜电极偶接时,球墨铸铁作为阳极,电偶腐蚀电流密度为其自腐蚀时的3.46倍;随着温度升高,电偶对的阳极腐蚀加剧;随着Sc:Sa的增大,电偶腐蚀电流密度增大;电化学噪声Ig-t和Eg-t谱揭示了电偶对的阳极保护膜被破坏、发生孔蚀时的电荷变化情况.电偶效应促进了阳极球墨铸铁点蚀的发生.
Galvanic Corrosion Behavior of Ductile Iron/H62 Brass in Water Distribution System
In order to investigate the galvanic corrosion of the connection between ductile cast iron and H62 brass water pipe in tap water supply network,electrochemical noise ( EN),EDS,SEM and other methods were used to investigate the galvanic corrosion current,corrosion mor-phology and corrosion product composition of ductile cast iron/H62 brass electrode at different temperatures ( 0 ℃,25 ℃,40 ℃) and the specific surface area ratios of anode and cathode ( Sc∶Sa=1∶1、2∶1、4∶1) under the condition of simulated acidic industrial atmospheric corrosion. Results showed that when the nodular cast iron/H62 brass electrode was coupled,the nodular cast iron served as the anode,and the galvanic corrosion current density was 3.46 times that of its self-corrosion process. The anode corrosion of couple pair was intensified with the increase of temperature. With the increase of Sc∶Sa,the galvanic corrosion current density increased. Furthermore,the Ig-t and Eg-t spectra of electrochemical noise revealed that the change in charge when the anode protection film of the electric couple pair was damaged and pitting occurred. Hence,the galvanic effect promoted the occurrence of pitting corrosion in anode ductile iron.

ductile ironH62 brassgalvanic corrosioncorrosion currentelectrochemical noise

汤甜、朱志平、唐韵子、刘健、毛春奎

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长沙理工大学化学化工学院,湖南 长沙 410114

长沙供水有限公司,湖南 长沙 410035

球墨铸铁 H62黄铜 电偶腐蚀 腐蚀电流 电化学噪声

湖南省教育厅科学研究重点项目

23A0269

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(7)