首页|Cr30钢表面镍包WC增强铁基合金涂层的微观组织和耐磨耐蚀性能研究

Cr30钢表面镍包WC增强铁基合金涂层的微观组织和耐磨耐蚀性能研究

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为改善Cr30钢表面的耐冲蚀磨损性能以及耐硫酸、盐酸腐蚀性能,以铁合金粉和镍包WC颗粒的混合物为原料,采用激光熔覆技术在Cr30钢表面制备含镍包WC铁基合金涂层,研究了原料中镍包WC质量分数(10%~30%)对铁基合金涂层的显微组织、物相组成、显微硬度、耐冲蚀磨损性能、耐硫酸和盐酸腐蚀性能的影响.结果表明:不含镍包WC的铁基合金涂层物相为FeCr固溶体和Cr23C6;含10%和20%镍包WC的铁基合金涂层物相为FeCr固溶体、Cr23C6和Fe3W3C;随着镍包WC含量增至30%,铁基合金涂层中析出了新的碳化物Fe6W6C,含30%镍包WC的铁基合金涂层物相为FeCr固溶体、Cr23C6、Fe3W3C和Fe6W6C.随着镍包WC含量的增加,铁基合金涂层的显微硬度、耐冲蚀磨损和耐硫酸、盐酸腐蚀性能提高,当镍包WC质量分数为30%时,铁基合金涂层的组织致密、细化效果最明显,涂层的硬度最高,达到786 HV0.5;30%镍包WC的铁基合金涂层的耐冲蚀磨损、耐硫酸和盐酸腐蚀性能最佳.
Microstructure,Wear and Corrosion Resistance Properties of Nickel-Coated WC Enhanced Iron-Based Alloy Coatings on Surface of Cr30 steel
In order to improve the erosion and wear resistance of Cr30 steel surface and its corrosion resistance to sulfuric acid and hydrochloric acid,a nickel-coated WC iron-based alloy coating was prepared on the surface of Cr30 steel by laser cladding technology with using a mixture of ferroalloy powder and nickel-coated WC particles as raw materials.The effects of the mass fraction of nickel-coated WC(10%~30%) in the raw material on the microstructure,phase composition,microhardness,erosion and wear resistance,and sulfuric acid and hydrochloric acid corrosion resistance of the iron-based alloy coating were studied.Results showed that the phases of the iron-based alloy coating without nickel-coated WC were FeCr solid solution and Cr23C6,while the phases of the iron-based alloy coating containing 10% and 20% nickel-coated WC were FeCr solid solution,Cr23C6 and Fe3W3C.As the content of nickel-coated WC increased to 30%,new carbides Fe6W6C were precipitated in the iron-based alloy coating,and the phases of the iron-based alloy coating containing 30% nickel-coated WC were FeCr solid solution,Cr23C6,Fe3W3C and Fe6W6C.Meanwhile,with the increase of the content of nickel coated WC,the microhardness,erosion wear resistance and sulfuric acid and hydrochloric acid corrosion resistance of iron-based alloy coating were improved.When the mass fraction of nickel coated WC was 30%,the microstructure of the iron-based alloy coating was dense and the refinement effect was most obvious,and the hardness of the coating was the highest,reaching 786 HV0.5 .In general,the iron-based alloy coating with 30% nickel-clad WC possessed the best resistance to erosion wear,sulfuric acid and hydrochloric acid corrosion.

laser claddingnickel coated WCiron-based alloy coatingerosion wearcorrosion in acidic media

汤联生、连应华、林星、郭岩

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福建华电可门发电有限公司,福建 连江 350512

华电电力科学研究院有限公司,浙江 杭州 310030

激光熔覆 镍包WC 铁基合金涂层 冲蚀磨损 酸性介质腐蚀

中国华电集团有限公司科技项目

CHDKJ22-02-103

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(8)