材料保护2024,Vol.57Issue(9) :28-35.DOI:10.16577/j.issn.1001-1560.2024.0198

Sr元素含量对Zn-2.0%Al-1.2%Mg镀层的微观组织与耐蚀性的影响

Effect of Sr Element Content on the Microstructure and Corrosion Resistance of Zn-2%Al-1.2%Mg Coating

林文军 欧阳志云 占杨方 苗华磊 刘洋 朱戴博
材料保护2024,Vol.57Issue(9) :28-35.DOI:10.16577/j.issn.1001-1560.2024.0198

Sr元素含量对Zn-2.0%Al-1.2%Mg镀层的微观组织与耐蚀性的影响

Effect of Sr Element Content on the Microstructure and Corrosion Resistance of Zn-2%Al-1.2%Mg Coating

林文军 1欧阳志云 2占杨方 1苗华磊 1刘洋 2朱戴博2
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作者信息

  • 1. 株洲冶炼集团股份有限公司,湖南 株洲 412000
  • 2. 湘潭大学机械工程与力学学院,湖南 湘潭 411110
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摘要

为了进一步研究微量合金元素对镀层微观组织的调控以及耐蚀性能的影响机理,采用双镀法在Q235钢板上制备Zn-2.0%Al-1.2%Mg-x%Sr(x=0、0.03%、0.06%、0.09%、0.12%,质量分数)镀层,通过扫描电子显微镜(SEM)、X射线衍射仪(XRD)、5%NaCl浸泡实验等方法探究Sr元素含量对Zn-2.0%Al-1.2%Mg镀层的微观组织与耐蚀性的影响.结果表明:添加适量的Sr元素,可以有效细化Zn-2.0%Al-1.2%Mg镀层表面凝固组织中的初生η-Zn相,引导生成Zn/Al/MgZn2三元共晶组织,使中间合金层中FeAl3-Znx柱状晶变得更加致密.当Sr的添加量为0.09%时,镀层表面凝固组织的细化效果最为明显,中间合金层最薄且致密,此时镀层的浸泡腐蚀速率最低,耐蚀性最好.

Abstract

In order to further investigate the regulation of trace alloying elements on the microstructure of coatings and the mechanism of their influence on corrosion resistance,a dual plating method was used to prepare Zn-2.0%Al-1.2%Mg-x%Sr (x=0,0.03%,0.06%,0.09%,0.12%,mass fraction) coatings on Q235 steel plates. The effects of Sr element content on the microstructure and corrosion resistance of Zn-2.0%Al-1.2%Mg coatings were examined through scanning electron microscopy (SEM),X-ray diffraction (XRD) and 5%NaCl immersion test. Results showed that adding an appropriate amount of Sr element could effectively refine the primary η-Zn phase in the solidifi-cation microstructure of the surface of Zn-2.0%Al-1.2%Mg coating,promoted the formation of a Zn/Al/MgZn2 ternary eutectic structure,and made the FeAl3-Znx columnar crystals in the intermediate alloy layer denser. Notably,when the addition amount of Sr was 0.09%,the refine-ment effect of solidification structure on the surface of the coating was most obvious,and the intermediate alloy layer was the thinnest and den-sest,at which time the coating had the lowest rate of immersion corrosion and the best corrosion resistance.

关键词

热浸镀/Zn-Al-Mg镀层/Sr/显微组织/耐蚀性

Key words

hot dip plating/Zn-Al-Mg coating/Sr/microstructure/corrosion resistance

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基金项目

株洲冶炼集团企业横向项目(ZYKJ20240425007)

出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
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