材料保护2024,Vol.57Issue(9) :63-70.DOI:10.16577/j.issn.1001-1560.2024.0202

Ni-W镀管在CO2注入井工况下的适用性研究

Study on the Applicability of Ni-W Coated Tubing in CO2 Injection Well Environments

马英文 邢希金 冯桓榰 杨芝乐 王竹
材料保护2024,Vol.57Issue(9) :63-70.DOI:10.16577/j.issn.1001-1560.2024.0202

Ni-W镀管在CO2注入井工况下的适用性研究

Study on the Applicability of Ni-W Coated Tubing in CO2 Injection Well Environments

马英文 1邢希金 1冯桓榰 1杨芝乐 2王竹2
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作者信息

  • 1. 中海油研究总院有限责任公司,北京 100028
  • 2. 北京科技大学新材料技术研究院,北京 100083
  • 折叠

摘要

为研究Ni-W镀管材料在CO2注入井工况下的适用性,采用高温高压腐蚀模拟实验,结合扫描电镜、激光共聚焦显微镜及X射线衍射仪研究了Ni-W镀层的腐蚀行为.结果表明,在含有杂质的超临界CO2注入工况下Ni-W镀层具有一定的耐均匀腐蚀能力,但存在局部腐蚀风险;在地层水反流的CO2注入井工况下,微量的H2S会诱发Ni-W镀层发生较为严重的腐蚀失效,造成镀层开裂和局部破损;在存在地层水反流的高含氧CO2注入井工况下,Ni-W镀层会形成微裂纹,并在内外镀层界面形成腐蚀产物.

Abstract

For studying the applicability of Ni-W coating in CO2 injection wells,the corrosion behaviors of Ni-W coatings were studied by high temperature and high-pressure corrosion simulation experiments combined with scanning electron microscope (SEM),laser confocal microscope and X-ray diffractometer (XRD) . Results showed that the Ni-W coating had certain uniform corrosion resistance under the condi-tion of supercritical CO2 containing impurities injection condition,but there was localized corrosion risk. In the case of CO2 injection well with formation water reflux,a small amount of H2S would induce severe corrosion failure of Ni-W coatings,resulting in cracking and local damage of the coating. In the case of high oxygenated CO2 injection well with formation water reflux,micro-cracks would be formed in Ni-W coatings,and corrosion products would be generated at the inner and outer coating interfaces.

关键词

CCUS/Ni-W镀层/超临界二氧化碳/腐蚀/硫化氢/氧含量

Key words

CCUS/Ni-W coating/super critical CO2/corrosion/H2S/O2 content

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基金项目

中国海洋石油有限公司综合科研项目(KJZH-2024-2301)

出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCDCSCD
影响因子:1.129
ISSN:1001-1560
参考文献量14
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