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某油田90℃井下环境中N80Q钢的CO2腐蚀行为

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为了给某油田针对实际地下腐蚀环境的选材提供参考建议,使用高压釜模拟了油田地下腐蚀环境90℃、1.0 m/s下5Mn2、1CrRE和2Cr钢生产的N80Q钢管的CO2腐蚀行为,使用扫描电子显微镜以及配套的能谱仪、X射线衍射仪对3种钢的腐蚀产物膜进行表征.结果表明:在90℃下这些钢种主要呈均匀腐蚀特征,平均腐蚀速率差异不大.腐蚀产物膜均呈双层结构,且较为致密,主要由FeCO3和少量FeOOH构成.研究提出,Fe3C在腐蚀产物膜中作为阳极可以生成FeCO3和 FeOOH,从而导致90 ℃下腐蚀速率显著下降.
CO2 Corrosion Behavior of N80Q Steels under 90℃ Underground Environment of Certain Oil Field
In order to provide reference suggestions for selection of materials for the actual underground corrosion environment of a certain oil field,a high-pressure autoclave was used to simulate the CO2 corrosion behavior of N80Q steel pipes prepared by the 25Mn2,1CrRE and 2Cr steel under 90 ℃ and 1.0 m/s in the underground corrosive environment of the oil field.Additionally,scanning electron microscopy,energy dispersive spectroscopy and X-ray diffraction were utilized to characterize corrosion product films of three types of steel.Results showed that the three steels mainly exhibited uniform corrosion characteristics at 90 ℃,and the difference in average corrosion rates was not significant.Meanwhile,the corrosion product films consisted of a relatively dense double-layered structure,and their composition were main FeCO3 and a small amount of FeOOH.The research suggested that Fe3C as an anode in the corrosion film could generate FeCO3 and FeOOH,which led to a significant decrease in corrosion rate at 90 ℃.

CO2 corrosionlow-alloy steelanodic protection effect

王奎、张玉玲、冯莹、田青超

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达力普石油专用管有限公司技术中心,河北 沧州 061113

上海大学省部共建高品质特殊钢冶金与制备国家重点实验室,上海 200444

CO2腐蚀 低合金钢 阳极保护作用

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(11)