材料保护2024,Vol.57Issue(11) :45-52.DOI:10.16577/j.issn.1001-1560.2024.0248

弯曲变形304L不锈钢在高温碱盐环境中的腐蚀行为研究

Study on the Corrosion Behavior of Bending Deformed 304L Stainless Steel in High-Temperature Alkali Salt Environment

史建波 陈永康 朱周杰 林奕锦 周和荣
材料保护2024,Vol.57Issue(11) :45-52.DOI:10.16577/j.issn.1001-1560.2024.0248

弯曲变形304L不锈钢在高温碱盐环境中的腐蚀行为研究

Study on the Corrosion Behavior of Bending Deformed 304L Stainless Steel in High-Temperature Alkali Salt Environment

史建波 1陈永康 1朱周杰 1林奕锦 2周和荣3
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作者信息

  • 1. 武汉武锅能源工程有限公司,湖北 武汉 430205
  • 2. 武汉科技大学材料学部,湖北 武汉 430081
  • 3. 武汉科技大学材料学部,湖北 武汉 430081;武汉科技大学省部共建耐火材料与冶金国家重点实验室,湖北武汉 430081
  • 折叠

摘要

为探究弯曲变形不锈钢复合管在锅炉碱盐环境中的腐蚀行为及性能变化规律,通过对材料组织、结构及腐蚀产物形貌、组成等分析,研究了 304L不锈钢在300℃含硫碱盐环境中的腐蚀行为,并重点分析了弯曲变形对304L不锈钢腐蚀性能的影响.结果表明:304L不锈钢在碱盐环境中试验48 h后表面腐蚀较轻微,腐蚀不均匀,腐蚀产物主要为Fe2O3、FeCr2O4和FeOOH,主要为元素铁和铬优先发生腐蚀;弯曲变形304L不锈钢腐蚀速率较大,腐蚀产物较厚,主要是弯曲变形使304L不锈钢小晶粒变形明显,位错和孪晶增加所致.

Abstract

For investigating the corrosion behavior and performance changes of bending deformation stainless steel composite pipes in boiler al-kali salt environment,the corrosion behavior of 304L stainless steel in 300 ℃ sulfur-containing alkali salt environment was studied through an-alyzing the material structure,morphology and composition of corrosion products,and the influence of bending deformation on the corrosion performance of 304L stainless steel was emphatically researched.Results showed that after 48 h of testing in alkaline salt environment,the sur-face corrosion of 304L stainless steel was relatively mild and uneven,and the main corrosion products were Fe2O3,FeCr2O4 and FeOOH,indi-cating that the corrosion primarily occurred on iron and chromium elements.Bent deformation of 304L stainless steel resulted in a higher corro-sion rate and thicker corrosion products,mainly due to the significant deformation of small grains and an increase in dislocations and twinning caused by bending deformation.

关键词

304L不锈钢/碱性介质/弯曲变形/腐蚀行为

Key words

304L stainless steel/alkaline medium/bending deformation/corrosion behavior

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出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCDCSCD
影响因子:1.129
ISSN:1001-1560
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