材料保护2024,Vol.57Issue(11) :93-100,109.DOI:10.16577/j.issn.1001-1560.2024.0253

深冷循环处理对铁基非晶涂层结构和摩擦磨损性能的影响

Effects of Deep Cryogenic Cycle Treatment on the Structure and Tribological Properties of Fe-Based Amorphous Coatings

赵建华 黄莉婷 庄曙东 田芳 纪秀林
材料保护2024,Vol.57Issue(11) :93-100,109.DOI:10.16577/j.issn.1001-1560.2024.0253

深冷循环处理对铁基非晶涂层结构和摩擦磨损性能的影响

Effects of Deep Cryogenic Cycle Treatment on the Structure and Tribological Properties of Fe-Based Amorphous Coatings

赵建华 1黄莉婷 1庄曙东 2田芳 2纪秀林3
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作者信息

  • 1. 河海大学 材料科学与工程学院,江苏常州 213022
  • 2. 河海大学 机电工程学院,江苏常州 213022
  • 3. 汕头大学机械工程系,广东汕头 515063
  • 折叠

摘要

针对铁基非晶涂层塑韧性差的问题,对铁基非晶涂层进行了不同循环次数的深冷循环处理,研究了 30次和60次深冷循环处理对涂层结构和摩擦磨损性能的影响.结果表明:深冷循环处理后,涂层仍与基体结合良好,呈典型的层状结构.深冷循环处理没有改变涂层的结构和非晶态本质,但提高了涂层的驰豫焓,涂层的自由体积含量增加,发生了回春现象.深冷循环处理的涂层在不同载荷(5,10,20 N)下的平均摩擦系数和磨损率均在30次时最低,H/E和H3/E2值最大,耐磨性最好.未处理涂层在不同载荷下的磨损机制以脆性剥落为主.深冷循环处理后,涂层的磨损机制由脆性剥落向磨粒磨损转变.深冷循环处理有助于提高铁基非晶涂层的耐磨性.

Abstract

To address the issue of poor plasticity and toughness of Fe-base amorphous coatings,deep cryogenic cycling treatment(DCT)was applied with varying numbers of cycles.The effects of 30 and 60 cycles of DCT on the structure and tribological properties of the coatings were studied.Results showed that the coating was still well adhered to the substrate and exhibited a typical layered structure after DCT.The structure and amorphous nature of the coating were not changed by DCT,but the relaxation enthalpy of the coating was increased.The free volume content of the coating was increased,and rejuvenation phenomenon was observed.The coating treated with 30 deep cryogenic cycles had the lowest average friction coefficient and wear rate,the highest H/E and H3/E2 values,and the best wear resistance under different loads(5,10,20 N).The wear mechanism of the untreated coating under different loads was mainly brittle spalling.After DCT,the wear mechanism of the coating was changed from brittle spalling to abrasive wear.Deep cryogenic cycle treatment was found to enhance the wear resistance of Fe-based amorphous coating.

关键词

铁基非晶涂层/深冷循环处理/结构/摩擦磨损

Key words

Fe-based amorphous coating/deep cryogenic cycle treatment/structure/tribology

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出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCDCSCD
影响因子:1.129
ISSN:1001-1560
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