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激光重熔功率对HVOF喷涂WC-Ni涂层耐磨性的影响

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为了探究微观组织结构的改变对涂层的硬度和耐磨性的影响,使用低成本的超音速火焰喷涂(HVOF)技术预沉积WC-Ni涂层,并利用50~150 W功率激光重熔后处理涂层,研究了激光重熔功率对WC-Ni涂层的显微组织、物相组成、显微硬度、耐磨损性能的影响.结果表明:采用150 W激光重熔后,涂层中的WC形成了蜂窝状骨架结构,使材料的韧性增强,可以显著抑制裂纹的生成和扩展;当激光功率较低时(50 W和100 W),涂层中并没有形成蜂窝状的骨架结构,但由于激光热作用,原始涂层扁平粒子之间的内聚力增强,硬度和耐磨性都有一定的提高.原始的WC-Ni涂层的硬度平均为327 HV0.2,50 W和100 W处理后涂层的硬度分别变为335 HV0.2和346 HV0.2.但150 W处理后的涂层中形成了均匀的蜂窝状WC骨架结构,且有部分WC和Ni形成了 Ni4W,故150 W处理后的涂层硬度略有降低(288 HV0.2),不过150 W处理后的涂层中的WC演变成了网状骨架结构,可以良好地抑制裂纹的形成与扩展,其磨损率最低,仅为3.544×10-5 mm3/(N·m),相较于WC-Ni涂层[2.025×10-4 mm3/(N·m)]、50 W[1.424×10-4 mm3/(N·m)]和 100 W[1.132×10-4 mm3/(N·m)]激光重熔后涂层的磨损率分别降低了 83.9%、75.1%和68.7%.蜂窝状WC-Ni结构涂层为开发耐磨材料提供了新的思路.
Effect of the Laser Remelting Power on the Wear Resistance of the WC-Ni Coatings Sprayed by HVOF
In order to investigate the effect of microstructural changes on the hardness and wear resistance of coatings,low-cost high-velocity oxygen-fuel spraying(HVOF)technology was used to pre-deposit WC-Ni coatings,and the coatings were treated by laser remelting at a power of 50~150 W.The influence of laser remelting power on the microstructure,phase composition,microhardness and wear resistance of WC-Ni coatings was studied.Results showed that after remelted by 150 W laser,the WC in the coating formed a honeycomb like skeleton structure,enhancing the toughness of the material and significantly suppressing the generation and propagation of cracks.When the laser power was low(50 W and 100 W),no honeycomb like skeleton structure was observed in the coating.However,due to the thermal effect of the laser,the co-hesion between the flat particles in the original coating was enhanced,and the hardness and wear resistance were improved to some extent.The average hardness of the original WC-Ni coating was 327 HV02,while the hardness of the coatings after 50 W and 100 W treatment increased to 335 HV02 and 346 HV02,respectively.Moreover,after 150 W treatment,a uniform honeycomb like WC skeleton structure was formed in the coating,and some WC and Ni formed Ni4W,thereby reducing slightly the hardness of the coating after 150 W treatment(288 HV02).The WC in the coating treated with 150 W evolved into a mesh like skeleton structure,which could effectively suppress the formation and propaga-tion of cracks,and the wear rate was the lowest,only 3.544×10-5 mm3/(N·m),This represented a reduction of 83.9%,75.1%,and 68.7%compared to the wear rates of the original WC-Ni coating[2.025 × 10-4 mm3/(N·m)]and coatings subjected to 50 W[1.424× 10-4 mm3/(N·m)]and 100 W[1.132×10-4 mm3/(N·m)]laser remelting,respectively.Overall,the WC-Ni coatings with honeycomb structure could provide a new approach for the development of wear-resistant materials.

laser surface remeltinghigh-velocity oxygen-fuelmetal ceramic coatinghoneycomb structurefriction and wear

乔振鑫、周平、赵菲、杨睿、李华

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太原科技大学材料科学与工程学院,山西太原 030024

中科院宁波材料技术与工程研究所慈溪医学生物医学工程研究所,浙江宁波 315300

激光表面重熔 超音速火焰喷涂 金属陶瓷涂层 蜂窝结构 摩擦磨损

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(11)