材料保护2024,Vol.57Issue(12) :114-121.DOI:10.16577/j.issn.1001-1560.2024.0276

改性TiO2防污闪复合涂层的制备与研究

Research on the Preparation of Modified TiO2 Composite Coatings with Anti-Fouling and Flashover Resistance

张杰 邹君文 刘学广 李小英
材料保护2024,Vol.57Issue(12) :114-121.DOI:10.16577/j.issn.1001-1560.2024.0276

改性TiO2防污闪复合涂层的制备与研究

Research on the Preparation of Modified TiO2 Composite Coatings with Anti-Fouling and Flashover Resistance

张杰 1邹君文 2刘学广 2李小英2
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作者信息

  • 1. 浙江省电力锅炉压力容器检验所有限公司,浙江 杭州 310000;国网浙江省电力有限公司电力科学研究院,浙江 杭州 310011
  • 2. 浙江省电力锅炉压力容器检验所有限公司,浙江 杭州 310000
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摘要

为有效降低输电线路绝缘子表面积污引起的污闪事故的发生,通过将改性纳米TiO2、PTFE与氟碳树脂FEVE结合,采用压缩空气喷涂技术制备出一种新型氟碳涂层材料,探讨了改性TiO2粒子的最佳添加量.采用扫描电镜(SEM)、原子力显微镜(AFM)研究了涂层的微观形貌,采用接触角测量仪对其疏水性、自清洁性及抗紫外老化性进行了分析.结果表明:改性纳米TiO2的最佳添加量为4%,涂层的附着力可达0级,静态水接触角最大为121°;TiO2经改性后制备的防污闪复合涂层表面存在大量微纳尺度的柱状锥尖结构,粗糙度更高,其疏水性更好,自清洁性、抗紫外老化性更佳,具备优良的防污闪性能.

Abstract

In order to effectively reduce the occurrence of pollution flashover accidents caused by surface contamination of transmission line in-sulators,a new fluorocarbon coating material was prepared by combining modified nano-TiO2,PTFE and fluorocarbon resin FEVE using com-pressed air spraying technology.The optimum addition amount of modified TiO2 particles was discussed.The microstructure was studied using scanning electron microscopy(SEM)and atomic force microscopy(AFM).The hydrophobicity,self-cleaning properties and anti-ultraviolet aging resistance were analyzed using a contact angle measurement instrument.The results showed that the optimum addition amount of modified nano-TiO2 was 4%,the adhesion of the coating reached grade 0,and the maximum static contact angle was 121°.The surface of the anti-pollu-tion flashover composite coating prepared with modified TiO2 exhibited numerous micro-nano scale columnar cone tip structures,resulting in higher roughness.Its hydrophobicity,self-cleaning ability,and anti-ultraviolet aging resistance were improved,demonstrating excellent anti-pollution flashover performance.

关键词

纳米TiO2改性/FEVE/自清洁/防污闪

Key words

modified nano-TiO2/FEVE/self-cleaning/anti-pollution flashover

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出版年

2024
材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCDCSCD
影响因子:1.129
ISSN:1001-1560
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