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飞机发泡胶除胶剂的研制

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在飞机机翼尾节板、扰流板等部位深度修理过程中,实现发泡胶高效清除又不损伤铝合金基材,在航空修理领域一直备受关注.在红外光谱、热重等试验分析发泡胶固化后产物的基础上,采用溶胀理论,确定二氯甲烷作为除胶剂的主溶剂.引入TiO2改性SiO2纳米微胶囊作为二氯甲烷的吸附剂及缓释剂,通过物理吸附、物理隔离及缓慢释放等方式,来实现减少VOC排放、延长除胶剂使用时间、提升脱胶性能.同时,采用石蜡和聚乙烯片进行表面阻隔,并在除胶剂的研制中加入Halox630缓蚀剂,有效地减缓除胶剂的挥发和对基材的腐蚀.结果表明,研制的除胶剂对铝合金表面残留发泡胶表现出优异的脱胶效果,同时对热固性胶粘剂表现出优异的软化、溶胀效果.
Development of Foam Adhesive Remover for Aircraft Applications
In the deep repair process of aircraft wing endplates,spoiler and other parts,the efficient removal of foam adhesive without dama-ging the aluminum alloy has been paid much attention in the field of aviation repair.In this study,the cured products of foam adhesive were an-alyzed using infrared spectroscopy and thermogravimetric analysis.Based on the swelling theory,dichloromethane was identified as the primary solvent for the adhesive remover.TiO2-modified SiO2 nanocapsules were introduced into dichloromethane as adsorbents and slow-release agents to reduce VOC emissions,extend the operating time of the adhesive remover,and improve its performance through mechanisms such as physi-cal adsorption,physical isolation and slow release.Meanwhile,paraffin and polyethylene sheets were used as surface barriers,and Halox630 corrosion inhibitor was added to the formulation of the adhesive remover to effectively reduce the volatilization of the remover and the corrosion of the substrate.Results showed that the developed foam adhesive remover exhibited excellent degumming performance on residual foam adhe-sive on the surface of aluminum alloy,as well as outstanding softening and swelling effects on thermosetting adhesives.

foam adhesiveremoverswelling theoryslow-releasecorrosion inhibitor

丁梦、朱浩、谭学才、蔡鹏、杨宗邦

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凌云科技集团有限责任公司,湖北 武汉 430040

凌云(宜昌)航空装备工程有限公司,湖北宜昌 444100

武汉工程大学材料科学与工程学院,湖北武汉 430074

发泡胶 除胶剂 溶胀理论 缓释 缓蚀

2024

材料保护
武汉材料保护研究所,中国腐蚀与防护学会 中国表面工程协会

材料保护

CSTPCD
影响因子:1.129
ISSN:1001-1560
年,卷(期):2024.57(12)