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棒状纳米碳酸钙的制备

Preparation of Stick-like Nano-CaCO3

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以无水三氯化铝(AlCl3)和乙二胺四乙酸(EDTA)为晶形控制剂和分散剂,采用碳化法制备了短径为40nm左右的棒状纳米碳酸钙,考察了AlCl3用量对产品形貌及产品性能(吸油值、沉降体积和活化度)的影响.结果表明,当AlCl3用量为1.5%时,所得的产品吸油值最低,为72mL/100g;当AlCl3用量为2.0%0时,所得产品沉降体积最大,达4.04mL/g;当AlCl3用量低于1.5%时,活化度随AlCl3用量的增加变化较小,而当AlCl3用量大于1.5%时,活化度随AlCl3用量的增加而明显降低.扫描电镜和X射线衍射仪显示,产品为方解石型棒状纳米碳酸钙.
The stick-like nano-CaCQ3 was prepared by carbonization, with A1Cl3 and EDTA as crystal control and dispering agent Effect of AlCl3 s content on product s apperance and performance such as DOP absorption, activation and sedimentation volume was studied. The results show that, when the amount of AlCl3 is 1. 5%, the DOP absorption comes to its lowest, it is 72mL/100gf when the amount of AlCl3 is 2. 0% and the amount of EDTA is 1%, the sedimentation volume comes to its highest, it is 4. 04mL/g; when the amount of AlCl3 is less than 1. 5%, the activation changes little with the increasing of AlCl3, when the amount of AlCl3 is more than 1. 5%, the activation rudu-ces obviously with the increasing of AlCl3. SEM and XRD show that the product is stick-like nano-CaCQ3.

stick-like nano-CaCQ3preparationactivationDOP absorptionsedimentation volume

张燕、吴国杰、崔英德

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仲恺农业工程学院化学化工学院,广州510225

棒状纳米碳酸钙 制备工艺 活化度 吸油值 沉降体积

广东省科技厅基金仲恺农业工程学院研究生创新基金

10151022501000033H1409002

2011

材料导报
重庆西南信息有限公司

材料导报

CSTPCDCSCD北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2011.25(20)
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