首页|SnO2/还原氧化石墨烯/聚苯胺三元复合物的合成及电化学性能

SnO2/还原氧化石墨烯/聚苯胺三元复合物的合成及电化学性能

扫码查看
采用两步法成功构筑SnO2/还原氧化石墨烯/聚苯胺(SnO2/RGO/PANI)三元复合材料.首先制备出均匀分散的SnO2/还原氧化石墨烯(SnO2/RGO)二元复合物,然后再以二元复合物为载体,通过苯胺(An)单体的化学氧化聚合获得终端产物.利用傅里叶红外光谱(FT-IR)、X射线衍射(XRD)和场发射扫描电镜(FESEM)对复合材料的结构和形貌等物理性质进行表征,利用循环伏安测试、恒电流充放电测试和交流阻抗测试对复合材料的电化学电容性能进行研究,并讨论了PANI的含量对复合材料的结构和性能的影响.结果表明,所合成的三元复合材料的比电容随PANI含量的增加而增大,最大达到424.8F/g,其电容性能的增强源于SnO2、RGO与PANI三者的相互协同作用.
Synthesis of SnO2/RGO/PANI Ternary Composites and Its Electrochemical Behaviors
SnO2 /RGO/PANI ternary composites were prepared by means of a two-step method including the synthesis of well-dispersed SnO2 /RGO and the in-situ chemical oxidative polymerization of aniline. Morphologies and microstructures of the resulting product were characterized by Fourier transform infrared (FT-IR) spectrometer. X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). Electrochemical behaviors of the ternary composites as a single electrode of supercapacitors were investigated by cyclic vojtammogram (CV), galvanos-tatic charge/discharge tests and electrochemical impedance techniques. The results show that the ternary composites exhibit a maximum specific capacitance of 424. BF/g, which is greater than the specific capacitance of SnCWRGO binary composites. Furthermore, specific capacitance of the sample increases with increasing amount of PANI in the ternary composites. The positive synergy effect between the three components might enhance the capacitive performance.

SnO2 /RGO/PANIternary compositesupercapacitorelectrochemical behavior

吴红英、张海英、张富海、梁鹏举、张亚军、胡中爱

展开 >

西北师范大学化学化工学院,甘肃省高分子材料重点实验室,生态环境相关高分子材料教育部重点实验室,兰州730070

SnO2/还原氧化石墨烯/聚苯胺 三元复合物 超级电容器 电化学性能

国家自然科学基金国家自然科学基金甘肃省自然科学基金

20963009211630170803RJA005

2012

材料导报
重庆西南信息有限公司

材料导报

CSTPCDCSCD北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2012.26(22)
  • 2
  • 5