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水滑石除磷的吸附动力学研究

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采用共沉淀法制备了Mg/Al水滑石,研究了不同Mg/Al物质的量比、材料用量、不同pH条件下Mg/Al水滑石吸附除磷的动力学特征,从而对吸附速率的控制过程进行分析.结果表明水滑石对磷的吸附能较好地符合准二级动力学方程、Elovich动力学方程和内扩散模型.n(Mg)/n(Al) =3是水滑石最理想配比,水滑石投加量越大,外扩散过程越慢;一定范围内pH的升高能促进水滑石对磷吸附速率和吸附容量的提升.
Kinetic Analysis for the Removal of Phosphorus onto Hydrotalcite by Adsorption
Hydrotalcite was prepared by the coprecipitation method.The adsorptive removal of phosphorus from aqueous solutions by calcined hydrotalcite was investigated in a batch mode.The influence of Mg/Al mole ratio,sorbent concentration and initial pH on the kinetics of phosphorus removal was tested in kinetic runs.Three kinetic models were used to fit the experimental data,and it was found that the pseudo-sencond-order kinetics model and Elovich model are most appropriate to describe the adsorption kinetics.n(Mg)/n(Al)=3 is the most ideal ratio of hydrotalcite.The more hydrotalcite we put,the slower the external diffusion of phosphorus is.Otherwise,the rise of pH in certain ranges can increase the adsorption rate and adsorption capacity.

hydrotalciteadsorptionkinetics

李晶、何欣、张瑶、王玉荣、陈金毅

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武汉工程大学化学与环境工程学院,武汉430073

水滑石 吸附 动力学

教育部新世纪优秀人才计划项目国家自然科学基金湖北省自然科学基金武汉工程大学研究生教育创新基金

NCET-12-0713513741572013CFA106CX2013108

2014

材料导报
重庆西南信息有限公司

材料导报

CSTPCDCSCD北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2014.28(22)
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