材料导报2025,Vol.39Issue(2) :17-24.DOI:10.11896/cldb.24020010

MXene对锌-空气电池双金属催化剂催化性能的影响

Effect of MXene on the Catalytic Performance of Bimetallic Catalysts for Zinc-Air Batteries

马润山 王海燕 张琦 杨建新 汤彬 李睿 李双寿 林万明 范晋平
材料导报2025,Vol.39Issue(2) :17-24.DOI:10.11896/cldb.24020010

MXene对锌-空气电池双金属催化剂催化性能的影响

Effect of MXene on the Catalytic Performance of Bimetallic Catalysts for Zinc-Air Batteries

马润山 1王海燕 2张琦 2杨建新 2汤彬 2李睿 2李双寿 2林万明 1范晋平1
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作者信息

  • 1. 太原理工大学材料科学与工程学院,太原 030024
  • 2. 清华大学基础工业训练中心,北京 100084
  • 折叠

摘要

开发高氧还原和氧析出性能、稳定和低成本阴极催化剂是实现锌-空气电池产业化的关键.本工作以FeCl3、NiCl2、ZnCl2和甲酰胺为原材料,采用水热合成-高温碳化-低温硫化的制备方法引入层状MXene材料,制备了 FeNiSNC7:3@MXene双金属复合材料作为锌-空气电池阴极催化剂,并分析了其物相组成、微观形貌、元素组成、电化学性能和电池性能.结果表明,使用这种催化材料制备的电池在电池测试中具有0.74 V的窄电压间隙,峰值功率密度达到179 mW/cm2,为二维材料与非贵金属催化剂结合提升锌-空气电池催化剂性能方面提供了新思路.

Abstract

The development of cathode catalysts with high oxygen reduction and oxygen evolution performance,stable and low-cost is the key to the industrialization of zinc-air batteries.In this work,FeNiSNC7:3@MXene bimetallic composites were prepared as cathode catalysts for zinc-air batteries using FeCl3,NiCl2,ZnCl2 and formamide as raw materials,and the phase composition,microscopic morphology,elemental composition,electrochemical properties and battery properties were analyzed by hydrothermal-synthesis,high-temperature,carbonization,low-temperature vulcanization.The battery prepared by this catalytic material has a narrow voltage gap of 0.74 V and a peak power density of 179 mW/cm2 in the battery test,which provides a new idea for the combination of two-dimensional materials and non-noble metal catalysts to improve the performance of zinc-air battery catalysts.

关键词

MXene材料/双金属复合材料催化剂/水热合成/高温碳化/低温硫化

Key words

MXene materials/bimetallic composite catalysts/hydrothermal synthesis/high-temperature carbonization/low-temperature vul-canization

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出版年

2025
材料导报
重庆西南信息有限公司

材料导报

CSCD北大核心
影响因子:0.605
ISSN:1005-023X
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