首页|MXene对锌-空气电池双金属催化剂催化性能的影响

MXene对锌-空气电池双金属催化剂催化性能的影响

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开发高氧还原和氧析出性能、稳定和低成本阴极催化剂是实现锌-空气电池产业化的关键。本工作以FeCl3、NiCl2、ZnCl2和甲酰胺为原材料,采用水热合成-高温碳化-低温硫化的制备方法引入层状MXene材料,制备了 FeNiSNC7:3@MXene双金属复合材料作为锌-空气电池阴极催化剂,并分析了其物相组成、微观形貌、元素组成、电化学性能和电池性能。结果表明,使用这种催化材料制备的电池在电池测试中具有0。74 V的窄电压间隙,峰值功率密度达到179 mW/cm2,为二维材料与非贵金属催化剂结合提升锌-空气电池催化剂性能方面提供了新思路。
Effect of MXene on the Catalytic Performance of Bimetallic Catalysts for Zinc-Air Batteries
The development of cathode catalysts with high oxygen reduction and oxygen evolution performance,stable and low-cost is the key to the industrialization of zinc-air batteries.In this work,FeNiSNC7:3@MXene bimetallic composites were prepared as cathode catalysts for zinc-air batteries using FeCl3,NiCl2,ZnCl2 and formamide as raw materials,and the phase composition,microscopic morphology,elemental composition,electrochemical properties and battery properties were analyzed by hydrothermal-synthesis,high-temperature,carbonization,low-temperature vulcanization.The battery prepared by this catalytic material has a narrow voltage gap of 0.74 V and a peak power density of 179 mW/cm2 in the battery test,which provides a new idea for the combination of two-dimensional materials and non-noble metal catalysts to improve the performance of zinc-air battery catalysts.

MXene materialsbimetallic composite catalystshydrothermal synthesishigh-temperature carbonizationlow-temperature vul-canization

马润山、王海燕、张琦、杨建新、汤彬、李睿、李双寿、林万明、范晋平

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太原理工大学材料科学与工程学院,太原 030024

清华大学基础工业训练中心,北京 100084

MXene材料 双金属复合材料催化剂 水热合成 高温碳化 低温硫化

2025

材料导报
重庆西南信息有限公司

材料导报

北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2025.39(2)