首页|植物源脲酶诱导碳酸钙沉积固化石灰石粉尘试验研究

植物源脲酶诱导碳酸钙沉积固化石灰石粉尘试验研究

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露天石灰石矿山的粉尘会导致空气、水和土壤污染,对人体健康和周围生态系统产生不利影响,制约着绿色矿山的建设和生产。为了解决这一问题,本工作基于酶诱导碳酸钙沉淀技术,利用大豆脲酶制备生物抑尘剂。从宏观和微观角度分析了生物抑尘剂对石灰石粉尘的固化效果,并揭示其固化机理。结果表明脲酶的活性与尿素浓度和温度密切相关,当胶结液浓度为0。8 mol·L-1时,生物抑尘剂的碳酸钙沉淀比最大,pH值为7。47,呈弱碱性。生物抑尘剂作用下的碳酸钙生成量显著提高,抑尘效率得到大幅提升。生物抑尘剂能够有效提高抗风蚀能力,在最高风速下抑尘效率达49。65%,最低风速下更是达到85。45%。此外,生物抑尘剂能有效减缓腐蚀速率,96 h达到0。020 mm/a,约为水的11。05%。脲酶诱导碳酸钙沉积(Enzyme-induced carbonate precipitation,EICP)的矿化产物主要为方解石型碳酸钙,具有充填、黏附、桥接和整体固化作用,能有效固化石灰石粉尘。研究表明EICP技术的经济性、环保性、可持续性以及对石灰石粉尘的积极影响使其成为一种具有极大潜力的解决方案。
Experimental Study on Plant-derived Urease-induced Calcium Carbonate Precipitation for Immobilizing Limestone Dusts
Dust in open-pit limestone mines can cause air,water,and soil pollution,adversely affect human health and surrounding ecosystems,and restrict the construction and production of green mines.To solve this problem,based on enzvme-induced carbonate precipitation technology,soybean urease was used to prepare a biological dust suppressant.The immobilization effect of biological dust suppressant on limestone dust was analyzed from macro and micro perspectives,and its immobilization mechanism was revealed.The results showed that the activity of urease was closely related to urea concentration and temperature.When the concentration of the cementing solution was 0.8 mol·L-1,the calcium carbonate precipitation ratio of the biological dust suppressant was the largest,with a pH of 7.47,indicating weak alkalinity.The production of calcium carbonate under the action of a biological dust suppressant was significantly improved,and the dust suppression efficiency was greatly improved.The biological dust suppressant can effectively improve the anti-wind erosion ability,and the dust suppression efficiency reaches 49.65%at the highest wind speed and 85.45%at the lowest wind speed.In addition,the biological dust suppressant can effectively slow down the corrosion rate,reaching 0.020 mm/a at 96 h,which is about 11.05%of water.The mineralization products of enzyme-induced carbonate precipitation(EICP)are mainly calcite calcium carbonate,which have the functions of filling,cementation,connection,and overall immobilization,and can effectively immobilize limestone dust.Studies have shown that the economy,environmental protection,sustainability,and positive impact on limestone dust of EICP technology make it a potentially promising solution for dust suppression.

enzyme-induced carbonate precipitationbiological dust suppressantlimestone dustswind erosion resistance testcuring mec-hanism

杜常博、陶晗、易富、黄惠杰、程传旺

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辽宁工程技术大学土木工程学院,辽宁阜新 123000

重庆交通大学土木工程学院,重庆 400074

北京京能地质工程有限公司,北京 102300

脲酶诱导碳酸钙沉积 生物抑尘剂 石灰石粉尘 抗风蚀测试 固化机理

2025

材料导报
重庆西南信息有限公司

材料导报

北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2025.39(2)