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混凝土全寿命周期固碳技术研究进展

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混凝土制备产生的碳排放占建筑业碳排放的28%,固碳技术成为实现"双碳"目标的关键。混凝土固碳技术是指利用CO2与混凝土孔溶液中碱金属离子(如Ca2+和Mg2+)或水化产物的碳化反应生成稳定的碳酸盐来实现CO2的封存。碳化反应会影响孔溶液、孔结构和水化产物的特性,进而影响混凝土的力学和耐久性能。本文围绕混凝土全寿命周期(拌合、养护、服役、二次利用),对混凝土固碳技术进行总结,对不同固碳技术的碳化机理、技术特点和固碳潜力进行了论述。拌合阶段注入CO2可促使混凝土主动碳化,但会消耗能量并产生新的碳排放。碳化养护可提高混凝土早期强度,但致密的碳化产物限制了碳化的进一步发展。服役阶段的碳化无需人为干预,固碳潜力大,但其碳化速率较低。二次利用阶段的碳化不仅可实现CO2封存,还可改善再生骨料的品质。对现有技术进行优化、引入新材料和新结构形式有助于提升全寿命周期混凝土的CO2封存效率。
Progress on Carbon Sequestration Technologies for the Full Life-cycle of Concrete
The carbon emissions generated by concrete preparation currently account for 28%of the total carbon release of the construction industry.The carbon sequestration technologies have become the key to achieving the"dual carbon"goals.Concrete carbon sequestration technologies refer to the utilization of carbonization reactions between CO2 and alkaline metal ions(such as Ca2+and Mg2+)or hydration products in concrete pore solutions generating stable carbonates to achieve the purpose of carbon immobilization.Carbonization reactions can affect concretes from the perspectives of characteristics such as pore solution,pore structure,and hydration products,thereby influencing the mechanical properties and durability of concrete.This paper summarizes the carbon sequestration technologies of concrete throughout its full life-cycle(mixing,curing,servicing,and secondary utilization),and systematically discusses the carbonization mechanism,technical characteristics,and storage potential of different carbon sequestration technologies.It has been clarified that injecting CO2 during mixing can promote the carbonization of concrete,but consumes energy and causes additional carbon emissions.Carbonization curing can improve the early strength of concrete,but the dense carbonization products limit the further development of carbonization.The carbonization of servicing concretes does not require human intervention and has great potential for carbon sequestration,but its process is relatively sluggish.The carbonization during the secondary utilization stage can not only achieve CO2 storage,but also improve the quality of aggregates.It is suggested that optimizing existing technologies and introducing new materials and structural forms can improve the CO2 immobilzation efficiency of concrete throughout its full life-cycle.

concretefull life-cyclecarbon sequestrationcarbonization mechanismcarbon curing"dual carbon"

杨海涛、练鑫晟、柳苗、孙国文、王伟

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石家庄铁道大学道路与铁道工程安全保障省部共建教育部重点实验室,石家庄 050043

石家庄铁道大学省部共建交通工程结构力学行为与系统安全国家重点实验室,石家庄 050043

石家庄铁道大学土木工程学院,石家庄 050043

混凝土 全寿命周期 固碳 碳化机理 碳化养护 "双碳"

2025

材料导报
重庆西南信息有限公司

材料导报

北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2025.39(2)