首页|OPC-SAC复合胶凝体系对超高性能混凝土性能的影响

OPC-SAC复合胶凝体系对超高性能混凝土性能的影响

扫码查看
针对超高性能混凝土(UHPC)在加固与修复工程中存在凝结时间长、早期强度发展缓慢等问题,将硫铝酸盐水泥(SAC)掺入超高性能混凝土中,研究了不同复配比例下OPC-SAC复合胶凝体系对UHPC力学性能与工作性能的影响,采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)及等温量热仪分别从水化产物的微观形貌、水化速率和水化放热量等方面分析了 OPC-SAC复合胶凝体系对UHPC水化过程与作用机理的影响。结果表明:SAC的掺入可大幅度降低UHPC的凝结时间和坍落度,且与基准组相比,当SAC掺量为10%时UHPC的初凝时间减少了329 min,终凝时间减少了 365 min,坍落度下降20 mm;随着SAC掺量的增加,UHPC的1 d抗压强度呈现先增大后减小的趋势,当掺入10%的SAC时,UHPC的1 d强度最高,且相比基准组高4。6%;掺入SAC后,UHPC的早期水化速率和放热量均高于基准组,且UHPC早期水化速率和放热量随着SAC掺量的增加均呈现增大的趋势;SAC的掺入使得复合胶凝体系内AFt的生成量增加,而Ca(OH)2的生成量减小,短时间内水化产物的生成量过多且分布不均匀,影响了混凝土强度。研究结果可为UHPC在加固与修复工程中的可喷射性提供理论依据。
Effect of OPC-SAC Composite Cementitious System on the Properties of Ultra-high Performance Concrete
Based on the problems such as long setting time and slow development of early strength of ultra-high performance concrete(UHPC)in reinforcement and restoration engineering,sulphoaluminate cement(SAC)was incorporated into ultra-high performance concrete,the effect of OPC-SAC composite cementitious system on the mechanical and working properties of UHPC under different compounding ratios were studied.Scanning electron microscopy(SEM),X-ray diffractometry(XRD)and isothermal calorimetry were used to analyze the effects of OPC-SAC composite cementitious system on the hydration process and mechanism of UHPC in terms of the microstructure of the hydration products,the hydration rate and the hydration heat release,respectively.Experimental results showed that the significant decrease in UHPC setting time and fluidity was due to the incorporation of SAC.When the SAC content was 10%,the initial setting time of UHPC was 329 min less than that of the baseline group,the final setting time was reduced by 365 min,and the slump was decreased by 20 mm.The 1 d compressive strength of UHPC increased first and then decreased with the increase of SAC content,when 10%SAC was added,the 1 d strength of UHPC was the highest,and 4.6%higher than that of the base group.After the addition of SAC,the early hydration rate and heat release of UHPC were higher than that of the reference group,and the hydration rate and heat release of UHPC in early stage showed an increasing trend with the increase of SAC content.The incorporation of SAC increased the generation of Aft and decreased the generation of Ca(OH)2 in the composite cementitous system,resulting in excessive generation and uneven distribution of hydration products within a short time,which affected the strength of UHPC.The output of this work can provide a theoretical basis for sprayability of UHPC in restoration and reinforcement engineering.

ultra-high performance concretecompound cement systemsetting timehydration process

王艳、李伊岚、杨子凡、常天风、孙琳琳

展开 >

西安建筑科技大学材料科学与工程学院,西安 710055

绿色建筑全国重点实验室,西安 710055

超高性能混凝土 复合胶凝体系 凝结时间 水化过程

2025

材料导报
重庆西南信息有限公司

材料导报

北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2025.39(2)