首页|稀土Ce对GCr15轴承钢中液析碳化物的影响

稀土Ce对GCr15轴承钢中液析碳化物的影响

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随着我国高端装备制造业的飞速发展,高端轴承钢材料的需求与研发日益迫切。目前GCr15轴承钢是应用最为广泛的高碳铬轴承钢之一,随着轴承钢洁净度的不断提高,液析碳化物对轴承钢性能的影响及其调控显得愈发重要。因此,本工作通过向GCr15轴承钢中添加稀土 Ce,研究其对轴承钢液析碳化物的影响及细质化调控机理。采用Thermo-Calc软件对GCr15轴承钢凝固过程中液析碳化物的析出行为进行热力学分析,利用XRD、OLS5100激光共聚焦显微镜、SEM-EDS等对GCr15轴承钢中液析碳化物的组成及微观形貌进行分析。结果表明,GCr15轴承钢中的液析碳化物类型主要为M3C、M7C3和M3C2;适量添加稀土 Ce可以明显降低液析碳化物数量和缩小尺寸,当GCr15轴承钢中稀土 Ce含量为320×10-6时,液析碳化物面积占比和最大尺寸分别降低了 3。22%和16。21 μm。此外,随着稀土 Ce含量的增加,液析碳化物的形核核心由MnS和Al2O3夹杂转变为尺寸较小的Ce-O-S稀土化合物,从而达到细质化调控液析碳化物的目的。
Effect of Rare Earth Ce on Primary Carbides in GCr15 Bearing Steel
With therapid development of high-end equipment manufacturing industry in China,the demand and research of high-quality bearing steel is increasingly urgent.Currently,GCr15 bearing steel is one of the most widely used high-carbon chromium bearing steels,the influence of primary carbides on bearing steel and control of primary carbides become more and more important with the continuous improvement of the cleanliness for bearing steel.Therefore,by adding rare earth Ce to GCr15 bearing steel,the effect of rare earth Ce on primary carbides in bearing steel was studied in this work.Thermo-Calc software was applied to thermodynamically analyze the precipitation behavior of primary carbides during solidification of GCr15 bearing steel.XRD,OLS5100 Laser Scanning Confocal Microscope and SEM-EDS were used to analyze the composition and microstructure of primary carbides in GCr15 bearing steel.The results showed that the typical primary carbides in GCr15 bearing steel were M3C,M7C3 and M3C2.The quantity and size of primary carbides could be obviously reduced with reasonable addition of rare earth Ce in GCr15 bearing steel.Especially when the content of rare earth Ce was 320×10-6,the area ratio and maximum size of primary carbides was reduced by 3.22%and 16.21 pm respectively.Moreover,with the increasing addition of rare earth Ce in GCr15 bearing steel,the nucleation core of primary carbides changed from MnS and Al2O3 to Ce-O-S with smaller size,which led to the refinement of primary carbides.

GCr15 bearing steelprimary carbidesrare earth Cemicrostructure

陈楠、汪宙、陈爽、李继文

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河南科技大学材料科学与工程学院,河南洛阳 471023

金属材料磨损控制与成型技术国家地方联合工程研究中心,河南洛阳 471023

有色金属新材料与先进加工技术省部共建协同创新中心,河南洛阳 471023

GCr15轴承钢 液析碳化物 稀土Ce 微观形貌

2025

材料导报
重庆西南信息有限公司

材料导报

北大核心
影响因子:0.605
ISSN:1005-023X
年,卷(期):2025.39(2)