首页|超双疏耐磨PPS基涂层的制备与性能

超双疏耐磨PPS基涂层的制备与性能

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以NH4HCO3为造孔剂,碳纳米管(CNTs)为纳米级纤维填料,采用简单的喷涂工艺制备出超双疏耐磨聚苯硫醚(PPS)基涂层。采用扫描电镜(SEM)、接触角测量仪分析涂层的表面形貌和疏水、疏油性能。采用定载砂纸打磨法测试双疏涂层的耐磨损性能。结果表明:造孔后的涂层表面粗糙,表面的多孔结构和CNTs构成了特殊的微纳二元复合网络结构。当NH4HCO3的含量为5%(质量分数)时,涂层实现超疏水和超疏油,对水、甘油和乙二醇的接触角分别为162°,158°和152°。用砂纸反复打磨10000次后,涂层表面轻微磨损,仍保持了高疏水效果,具有良好的耐磨性能。
Preparation and Properties of Superamphiphobic Wear-resistance PPS-based Coating
Superamphiphobic wear-resistance PPS-based coatings were prepared by a simple spraying method with a pore-forming reagent of NH4 HCOa and nano-filler of carbon nanotubes (CNTs).The surface morphology and the hydrophobicity,oleophobicity of the coating were analyzed by scanning electron microscope (SEM) and contact angle meter.The wear-resistance of the coating was verified by sanding method with given load.The results indicate that a rough surface is obtained after poreforming,and the porous structures in combination with the CNTs construct the special micro/nanoscale network structures.When the mass fraction of NH4 HCO3 is 5%0,the contact angles of the coating for water,glycerine and ethylene glycol are 162°,158° and 152°,showing superamphiphobic property.After polished 10000 times by abrasive paper,the coating shows slight friction marks and remains high hydrophobicity,exhibiting excellent wear-resistance.

superamphiphobicitycomposite materialpolyphenylene sulfidewear-resistancenano structuresurface

汪怀远、王恩群、孟旸、朱艳吉

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东北石油大学化学化工学院,黑龙江大庆163318

超双疏 复合材料 聚苯硫醚 耐磨 纳米结构 表面

国家自然科学基金资助项目黑龙江省杰出青年科学基金资助项目东北石油大学研究生创新科研项目

51175066JC201403YJSCX2014-021NEPU

2017

材料工程
中国航发北京航空材料研究院

材料工程

CSTPCDCSCD北大核心EI
影响因子:0.78
ISSN:1001-4381
年,卷(期):2017.45(1)
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