材料工程2024,Vol.52Issue(5) :163-170.DOI:10.11868/j.issn.1001-4381.2022.000431

CdS/rGO复合气凝胶的自组装合成及光催化降解盐酸四环素性能

Self-assembly synthesis of CdS/rGO composite aerogels and its photocatalytic degradation of tetracycline hydrochloride

刘文君 王倩雯 王代芳 沈丽宫 曹晓
材料工程2024,Vol.52Issue(5) :163-170.DOI:10.11868/j.issn.1001-4381.2022.000431

CdS/rGO复合气凝胶的自组装合成及光催化降解盐酸四环素性能

Self-assembly synthesis of CdS/rGO composite aerogels and its photocatalytic degradation of tetracycline hydrochloride

刘文君 1王倩雯 1王代芳 1沈丽宫 1曹晓1
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作者信息

  • 1. 福建生物工程职业技术学院,福州 350007
  • 折叠

摘要

以L-赖氨酸为还原剂和交联剂,采用一步水热法制备嵌入CdS纳米薄片(CdS NSs)的三维CdS/还原氧化石墨烯(CdS/rGO)复合气凝胶.结果表明:CdS/rGO复合气凝胶大的比表面积BET(Brunauer-Emmett-Teller,BET)和海绵状性质可增强对污染物的吸附,且其质量轻可漂浮在水面上可增强对光的吸收,同时rGO的引入促进了光生电荷的分离,使该复合气凝胶的光催化性能得到明显提升.在可见光照射下,CdS/rGO复合气凝胶可以在45 min内将盐酸四环素(tetracycline hydrochloride,TC)完全降解,1.5 h后几乎所有TC都已经矿化.此外,CdS/rGO复合气凝胶还显示出高稳定性并且容易从反应体系中分离出来,进行回收循环使用.经过5次循环使用后,CdS/rGO复合气凝胶的光催化活性没有明显降低.

Abstract

A CdS/reduced graphene oxide (rGO) composite aerogel with CdS nanosheets (CdS NSs) grown on an interconnected three-dimensional rGO-based porous network was prepared by one-pot hydrothermal method using L-lysine as a reducing agent and the cross-linker.The results show that its enhanced adsorption toward pollutants owing to its large Brunauer-Emmett-Teller specific surface area and spongy nature,and improved light absorption due to its extremely light weight nature.Moreover,the rGO promotes the photogenerated charge separation.Thus,the CdS/rGO composite aerogel exhibits enhanced activity for photocatalytic degradation.It can be observed that the tetracycline hydrochloride (TC) has been degraded totally after 45 min by irradiated CdS/rGO composite aerogel,and almost all TC has been mineralized after 1.5 h.Moreover,the CdS/rGO composite aerogel also shows high stability and can be easily separated from the reaction systems for recycling.The photocatalytic reduction activity of CdS/rGO composite aerogel shows no obvious decrease after 5 cycles.

关键词

rGO气凝胶/CdS/光催化/盐酸四环素/回收

Key words

RGO aerogel/CdS/photocatalysis/tetracycline hydrochloride/recycle

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基金项目

福建省自然科学基金(2019J05131)

福建省中青年教师教育科研项目(JAT220629)

出版年

2024
材料工程
中国航发北京航空材料研究院

材料工程

CSTPCDCSCD北大核心
影响因子:0.78
ISSN:1001-4381
参考文献量2
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