材料工程2024,Vol.52Issue(6) :51-58.DOI:10.11868/j.issn.1001-4381.2022.000196

MXene/芳纶纳米纤维柔性自支撑电极的构建及其在超级电容器中的应用

Construction of flexible MXene/aramid nanofibers self-supporting electrodes and application in supercapacitors

王思凡 郭雪 张钰欣 魏取福
材料工程2024,Vol.52Issue(6) :51-58.DOI:10.11868/j.issn.1001-4381.2022.000196

MXene/芳纶纳米纤维柔性自支撑电极的构建及其在超级电容器中的应用

Construction of flexible MXene/aramid nanofibers self-supporting electrodes and application in supercapacitors

王思凡 1郭雪 1张钰欣 1魏取福1
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作者信息

  • 1. 江南大学生态纺织教育部重点实验室,江苏无锡 214122
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摘要

随着可穿戴电子产品的微型化发展,开发轻柔、灵活、体积小、能量密度高的柔性储能器件成为研究的热点.以芳纶纳米纤维(aramid nanofiber,ANF)作为纤维增强柱撑材料,采用真空抽滤的方法制备MXene/ANF柔性自支撑电极,避免引入集流体和黏合剂等"死体积",并将其组装成全固态对称超级电容器.随着ANF含量增加至15%(质量分数),MXene/ANF自支撑电极的拉伸断裂强度增加至151.5 MPa,而电导率降低至1371.1 S/cm,在1 A/g的电流密度下表现出432.7 F/g的高比电容.组装的柔性对称全固态超级电容器的能量密度为25.7 Wh/kg,对应的功率密度为523.1 W/kg,具有优异的柔韧性和长循环寿命(10000周次循环充放电后,电容保持率为88.9%).

Abstract

With the development of miniaturized wearable electronics,flexible energy storage devices with soft,flexible,small size,and high energy density have attracted widespread attention. Aramid nanofibers (ANF) were utilized as fiber reinforcement and pillared structure materials to prepare MXene/ANF flexible self-supporting electrode through vacuum filtration,which were subsequently assembled into all-solid-state symmetric supercapacitors.With the increase of ANF content to 15%,the mechanical properties of MXene/ANF self-supporting electrode increase to 151.5 MPa,while the conductivity decrease to 1371.1 S/cm. The MXene/ANF Self-supporting electrode shows a high specific capacitance of 432.7 F/g at the current density of 1 A/g. The assembled symmetric all-solid-state supercapacitors exhibit excellent mechanical flexibility and remarkable cycling stability,with an energy density of 25.7 Wh/kg at the power density of 523.1 W/kg and about 88.9% capacitance retention over 10000 cycles.

关键词

芳纶纳米纤维/MXene/纤维增强/柔性自支撑电极/全固态超级电容器

Key words

aramid nanofiber/MXene/fiber reinforcement/flexible self-supporting electrode/all-solid-state supercapacitor

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基金项目

江苏省自然科学基金项目(BK20180628)

出版年

2024
材料工程
中国航发北京航空材料研究院

材料工程

CSTPCDCSCD北大核心
影响因子:0.78
ISSN:1001-4381
参考文献量33
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