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动态人工模拟海水环境下两种B10铜镍合金腐蚀行为

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采用动电位极化曲线和电化学阻抗谱测试并结合XPS测试和SEM/EDS微观表征,通过自制的冲刷腐蚀实验装置研究了两种B10铜镍合金在不同流速和不同时间下的冲刷腐蚀行为,比较了两种铜镍合金在不同冲刷条件下的腐蚀差异.结果表明,两种铜镍合金的腐蚀速率随时间的变化规律相似,在不同的流速下冲刷2 h后腐蚀速率较高,冲刷8 h后腐蚀速率较低.在低于4 m/s的流速冲刷不同时间后,A合金的耐蚀性整体上高于B合金的耐蚀性;当流速高于3 m/s且较长时间冲刷后,B合金的耐蚀性更好.这与钝化膜中Ni,Fe的化学态无关而与晶粒尺寸和孪晶数量以及Ni,Fe元素的富集有关.长时间高流速冲刷会促进钝化膜中Ni和Fe元素的富集,有利于增强钝化膜的耐蚀性.
Corrosion behavior of two B10 Cu-Ni alloys in dynamic simulated seawater
The erosion corrosion behavior of two B10 Cu-Ni alloys in a dynamic seawater environment under different flow velocities and erosion time was investigated by using electrochemical techniques and SEM/EDS in a self-made experimental device for erosion corrosion. The results demonstrate that the variation of the corrosion rate of the two alloys with time is similar. The corrosion rate of the two alloys is higher after two hours of immersion and lower after being immersed for eight hours at different velocities. The corrosion resistance of alloy A is generally higher than that of alloy B after being immersed at a flow velocity below 4 m/s for different time. When the flow velocity is higher than 3 m/s and flushing for a long time,the corrosion resistance of alloy B is better. It is related to the grain size and number of twins,as well as the enrichment of Ni and Fe,rather than the chemical states of Ni and Fe. Moreover,Ni and Fe are enriched in the passivation film of the two alloys after long-time immersion at a high flow velocity,which is beneficial for enhancing the corrosion resistance of the passivation film.

B10 Cu-Ni alloyelectrochemical techniqueerosion corrosionpassivation filmcorrosion morphology

苏英、管勇

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中国科学技术大学材料科学与工程学院,合肥 230026

中国科学院金属所,沈阳 110016

B10铜镍合金 电化学技术 冲刷腐蚀 钝化膜 腐蚀形貌

2024

材料工程
中国航发北京航空材料研究院

材料工程

CSTPCD北大核心
影响因子:0.78
ISSN:1001-4381
年,卷(期):2024.52(6)