材料工程2024,Vol.52Issue(10) :106-116.DOI:10.11868/j.issn.1001-4381.2022.000712

热处理对富锆α型TiZrAl合金组织和性能的影响

Effect of heat treatment on microstructures and properties of Zr-rich α TiZrAl alloy

傅霄云 武保林 徐再东 万刚 李洲 李健博
材料工程2024,Vol.52Issue(10) :106-116.DOI:10.11868/j.issn.1001-4381.2022.000712

热处理对富锆α型TiZrAl合金组织和性能的影响

Effect of heat treatment on microstructures and properties of Zr-rich α TiZrAl alloy

傅霄云 1武保林 1徐再东 1万刚 1李洲 1李健博1
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作者信息

  • 1. 沈阳航空航天大学材料科学与工程学院,沈阳 110136
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摘要

针对2种富锆α型钛合金(Ti60Zr40)97Al3(质量分数/%,下同)和(Ti50Zr50)97Al3,利用光学显微镜(OM)、差示扫描量热仪(DSC)、X射线衍射仪(XRD)、扫描电子显微镜(SEM)及室温拉伸等实验手段,分析研究了不同热处理工艺下2种合金的组织和性能.结果表明,经850℃/40 min退火后,合金为α网篮组织,并在α相间留有少量网状β相;经850℃/40 min水冷淬火,形成细针状α'马氏体;经850℃/40 min淬火+600℃/4 h时效后,在淬火中形成的细小针状α'马氏体转变成α相,然而马氏体转变不完全,形成α+α'remain组织.T40Z3A合金的拉伸屈服强度可达1100 MPa,并具有7%良好的伸长率;T50Z3A合金虽然具有更高的强度,但其塑性较差.分析表明,由于更高的Zr含量,T50Z3A合金在退火后具有更多的网状β相、淬火时效后具有更多残留α'马氏体相,导致其抗拉强度较高、塑性较差.

Abstract

The microstructures and properties of two kinds of zirconium-enriched α alloys (Ti60Zr40)97Al3 (mass fraction/%,the same below) and (Ti50Zr50)97Al3 via different heat treatments were investigated and analyzed based on optical microscope (OM) observation,differential scanning calorimetric (DSC) measurement,X-ray diffraction (XRD) measurement,scanning electron microscope (SEM) observation and tensile tests at room temperature.The results show that after 850 ℃/40 min annealing,microstructures consisting of basket-weave α phase and a small amount of reticular β phase are formed in the alloys. After 850 ℃/40 min quenching,the acicular α' martensite phase is formed. After 850 ℃/40 min quenching and then 600 ℃/4 h aging,a large part of α' martensite phase converts into α phase,and the microstructures of the alloys consist of α and α'remain phases. The yield strength of the T40Z3A alloy can reach 1100 MPa,with a favourable tensile elongation of 7%. The T50Z3A alloy exhibits higher strength but lower ductility than those of the T50Z3A alloy. Due to the higher content of Zr element,the T50Z3A alloy has more reticular β phase after annealing and more remaining α' martensite phase after quenching and aging,which results in higher strength and lower ductility.

关键词

钛锆合金/退火/淬火时效/相转变/组织/力学性能

Key words

Ti-Zr alloy/annealing/quenching and aging/phase transformation/microstructure/mechanical property

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出版年

2024
材料工程
中国航发北京航空材料研究院

材料工程

CSTPCDCSCD北大核心
影响因子:0.78
ISSN:1001-4381
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