材料工程2024,Vol.52Issue(10) :127-138.DOI:10.11868/j.issn.1001-4381.2023.000659

不同预制体结构制备C/C-SiC复合材料的微观结构演变及力学性能

Microstructure evolution and mechanical properties of C/C-SiC composites prepared with different prefabricated structures

魏琰斌 王雅雷 熊翔 叶志勇 刘在栋
材料工程2024,Vol.52Issue(10) :127-138.DOI:10.11868/j.issn.1001-4381.2023.000659

不同预制体结构制备C/C-SiC复合材料的微观结构演变及力学性能

Microstructure evolution and mechanical properties of C/C-SiC composites prepared with different prefabricated structures

魏琰斌 1王雅雷 1熊翔 1叶志勇 1刘在栋1
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作者信息

  • 1. 中南大学轻质高强结构材料重点实验室,长沙 410083
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摘要

采用缝合结构与针刺结构碳纤维预制体,经化学气相渗透法(CVI)和反应熔渗法(RMI)制备出C/C-SiC复合材料,系统研究了两种结构预制体制得的C/C多孔体微观结构、孔隙特征及C/C-SiC复合材料微观结构和弯曲性能.结果表明:缝合结构C/C多孔体孔径呈双峰分布,孔隙多为纤维束间孔,针刺结构C/C多孔体孔径呈单峰分布,由于网胎的加入使得部分纤维束间孔转变为连通的小孔隙网络,经过模拟后者Z向绝对渗透率略大于前者,有利于后者后续RMI致密化过程(高密度,低开孔率,低残余金属);缝合结构C/C-SiC复合材料平均弯曲强度高于针刺结构C/C-SiC复合材料,二者都呈现"假塑性"断裂方式;针刺结构C/C-SiC复合材料密度更高,残余Si含量更低,但其纤维体积含量较低,长直纤维的完整性较差,使得复合材料承载性能较低.

Abstract

C/C-SiC composites were prepared by chemical vapor infiltration (CVI) and reactive melt infiltration (RMI) using carbon fiber preforms with stitched and needle-punched structures. The microstructure and pore characteristics of C/C porous composites obtained from the two structural preforms,as well as the microstructure and flexural properties of C/C-SiC composites,were systematically studied. Results show that the pore size of stitched C/C porous composite is multimodal distribution,and the pores are mostly inter-bundle pores. The pore size of needle-punched C/C porous composite is unimodal distribution. Due to the addition of mesh,some inter-bundle pores are transformed into connected small pore networks. The simulated absolute permeability in the Z direction of the latter is slightly greater than that of the former,which is conducive to the subsequent RMI densification process of the latter (high density,low open-porosity and low residual metal). The average flexural strength of stitched C/C-SiC composites is higher than that of needle-punched C/C-SiC composites,both of which exhibit a "pseudo plastic" fracture mode. The needle-punched C/C-SiC composite has a higher density and lower residual Si content,but its fiber volume content is lower,and the integrity of long straight fibers is poor,resulting in lower load-bearing property of the composite.

关键词

C/C-SiC复合材料/孔隙结构/微观结构/弯曲性能

Key words

C/C-SiC composites/pores structure/microstructure/flexural property

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出版年

2024
材料工程
中国航发北京航空材料研究院

材料工程

CSTPCDCSCD北大核心
影响因子:0.78
ISSN:1001-4381
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