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水性聚苯胺微乳液及其防腐涂料研究

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利用改进的新型微乳液聚合法合成了聚苯胺水性微乳液,该微乳液不经破乳可直接应用于金属防腐涂料. 将其与环氧树脂的共混乳液作为底漆、与环氧树脂面漆复合后,可制备出性能优良的水性金属防腐涂料.该复合涂层能将裸露钢板的平衡开路电位提高235mV左右,在自来水中至少可浸泡3个月不起泡、不生锈,是一种环境友好型绿色涂料.
Studies on Waterborne Polyaniline Microlatex and its Coating for Metal Protection
A waterborne polyaniline microlatex is synthesized by a new modified microemulsion polymerization and the resulting microlatex could be applied as a coating for metal protection without further demulsification. A waterborne metal corrosion-resistant coating with good performance has been assembled using a mixture of the polyaniline microlatex with an epoxy emulsion as a prime coating, and a pure epoxy emulsion as a surface coating. The composite coating could enhance the open-circuit potential of a mild steel panel to circa 235mV comparing with that of the bare ones. They have not become blistered or rusted when they are exposed in tap-water for at least 3 months. It is indicated that the polyaniline microlatex is a sort of environmental friend coating.

PolyanilineWaterborne coatingCorrosion-resistant coating

黄美荣、杨海军、李新贵

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同济大学材料学院混凝土材料研究实验室材料化学研究所,上海,200092

聚苯胺 水性涂料 防腐涂料

2005

材料开发与应用
洛阳船舶材料研究所 中国造船工程学会船舶材料学术委员会

材料开发与应用

影响因子:0.342
ISSN:1003-1545
年,卷(期):2005.20(2)
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