Abstract
The surface properties of weathering steel (WS) is very important for its service performance and safety,and the localized corrosion induced by inclusions is closely related to the surface properties of WS and its application.In the current work,a common spherical (Al,Mg,Ca,Mn)-oxy-sulfide inclusion was selected to investigate the corrosion evolution of complex inclusion and its effect on localized corrosion on WS surface.The results indicate the inclusion in WS consists of (Ca,Mn) sulfides part and (Ca,Al,Mg) oxides part with complex core-shell structure.Locally preferential dissolution occurs in (Ca,Mn) sulfides part as well as metal matrix around the inclusions.Furthermore,both parts of the inclusions with poor conductivity and high-density dislocation at metal matrix around the inclusions was found,which suggests that traditional micro-galvanic corrosion cell may not be the cause of inclusion-induced localized corrosion on WS surface at initial stage of corrosion.The variation in maximum and average depth around the inclusion or selected region with immersion time indicates that localized corrosion induced by inclusions is overwhelmed by uniform corrosion of WS in the latter stage of immersion,then the rust formed on WS surface consists of two layers.
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