Abstract
Tremendous demands for highly sensitive and stable seawater salinometers have motivated intensive research on advanced electrode materials.Boron-doped diamond(BDD)is attractive in terms of its high mechanical stability and chemical inertness,but is usually hindered by its low double-layer capacitance(Cdl)for seawater salinity detection.Here,inspired by the principle of oxygen-terminated BDD electrode endowing higher Cdl than hydrogen-terminated surface,we introduce the oxygen terminated surface by oxygen plasma or reactive ion etch(RIE),and the fabricated oxygen terminated BDD electrodes demon-strate high sensitivity and long-term stability in seawater salinity detection comparing with the hydrogen terminated BDD electrodes.Significantly,the as-fabricated O-BDD-RIE electrodes not only show remark-able enhanced response even better than the commercial platinum black electrodes but also display long-time stability which is weekly verified by continuous monitor for 90 days.The outstanding per-formance of the oxygen terminated BDD electrodes can be ascribed to the enhancement of C-0 surface functional group on Cdl.In addition,a comprehensive analysis of effective electroactive surface area(EASA)and Cdl proves that the surface oxygen is the major factor for the improved Cdl.In summary,the excellent oxygen terminated BDD electrodes promise potential application in seawater salinity detection.
基金项目
This work was financially supported by the Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science(20180510009)
Young Talent Program of Shenyang National Laboratory for Materials Science(L2019F39)
and the National Natural Science Foundation of China(51202257)
NETL
NSTL
维普
万方数据